Porous, absorbent macrostructures of bonded absorbent particles surface crosslinked with cationic amino-epichlorohydrin adducts

ABSTRACT

Porous, absorbent macrostructures that, upon contacting liquids such as water or body exudates (e.g., urine), swell and imbibe such liquids, and are useful in absorbent articles such as diapers, adult incontinence pads, and sanitary napkins are disclosed. These porous macrostructures comprise bonded absorbent particles that are surface crosslinked with cationic, preferably polymeric, amino-epichlorohydrin adducts.

FIELD OF THE INVENTION

This application relates to porous, absorbent macrostructures that, uponcontacting liquids such as water or body exudates (e.g., urine), swelland imbibe such liquids, and are useful in absorbent articles such asdiapers, adult incontinence pads, sanitary napkins, and the like. Thisapplication particularly relates to porous macrostructures of bondedabsorbent particles that are surface crosslinked with cationic,preferably polymeric, amino-epichlorohydrin adducts.

BACKGROUND OF THE INVENTION

Particulate, absorbent, polymeric compositions are capable of absorbinglarge quantities of liquids such as water and body exudates (e.g.,urine) and are further capable of retaining such absorbed liquids undermoderate pressures. The absorption characteristics of such polymericcompositions make them especially useful for incorporation intoabsorbent articles such as diapers. See, for example, U.S. Pat. No.3,699,103 (Harper et al), issued Jun. 13, 1972, and U.S. Pat. No.3,770,731 (Harmon), issued Jun. 20, 1972, that disclose the use ofparticulate, absorbent, polymeric compositions (often referred to as"hydrogels", "superabsorbents", or "hydrocolloid materials") inabsorbent articles.

Conventional particulate, absorbent, polymeric compositions, however,have the limitation that the particles are not immobilized and are freeto migrate during processing and/or use. Migration of the particles canlead to material handling losses during manufacturing as well asnonhomogeneous incorporation of the particles into structures in whichthe particles are being used. A more significant problem, though, occurswhen these particulate materials migrate during or after swelling inuse. Such mobility leads to high resistance to liquid flow through thematerial due to the lack of stable interparticle capillary or liquidtransport channels. This phenomenon is one form of what is commonlyreferred to as "gel blocking."

One attempt to overcome the performance limitations associated withabsorbent particle mobility during use in absorbent articles isincorporation of the particulate, absorbent, polymeric compositions intotissue laminates, i.e. layered absorbent structures. By encapsulatingthe particles between tissue layers, the overall particle mobilitywithin an absorbent structure is diminished. However, upon liquidcontact, the particles within the laminate are often free to moverelative to each other resulting in the breakdown of any preexistentinterparticle capillary channels.

Another attempted solution is to immobilize the particulate, absorbent,polymeric compositions by the addition of large quantities of liquidpolyhydroxy compounds that act as an adhesive to hold the particlestogether or to a substrate. See, for example, U.S. Pat. No. 4,410,571(Korpman), issued Oct. 18, 1983. While this approach does limitmigration before and, to some extent, during swelling, the particleseventually become detached from each other in the presence of excessliquid, resulting again in the breakdown of any preexisting capillarychannels between the particles.

Another attempted solution to overcome the problem of absorbent particlemobility is to produce a superabsorbent film by extrusion of a solutionof a linear absorbent polymer and subsequently crosslinking it. See, forexample, U.S. Pat. No. 4,861,539 (Allen et al), issued Aug. 29, 1989(crosslinked with a polyhydroxy compound such as a glycol or glycerol);and U.S. Pat. No. 4,076,673 (Burkholder), issued Feb. 28, 1978(crosslinked with polyamine-polyamide epichlorohydrin adducts such asKymene®). While these superabsorbent films may absorb significantquantities of liquids, they have limited liquid transport propertiesbecause they are essentially nonporous, i.e. lack internal capillarychannels. Indeed, due to the lack of internal capillary channels, thesesuperabsorbent films are especially prone to gel blocking.

A more recent solution proposed to overcome the problem of absorbentparticle mobility is to form these particles into aggregatemacrostructures, typically as sheets of bonded absorbent particles. SeeU.S. Pat. No. 5,102,597 (Roe et al), issued Apr. 7, 1992. Theseaggregate macrostructures are prepared by initially mixing the absorbentparticles with a solution of a nonionic crosslinking agent, water and ahydrophilic organic solvent such as isopropanol. These nonioniccrosslinking agents include polyhydric alcohols (e.g., glycerol),polyaziridine compounds (e.g., 2,2-bishydroxymethylbutanoltris[3-(1-aziridine) propionate]), haloepoxy compounds (e.g.,epicholorhydrin), polyaldehyde compounds (e.g., glutaraldehyde),polyamine compounds (e.g., ethylene amine), and polyisocyanate compounds(e.g., 2,4-toluene diisocyanate), preferably glycerol. See Column 11,lines 22-54, of Roe et al.

Particulate absorbent polymer compositions of the type used in makingthese aggregate macrostructures usually contain multiple carboxy groupsand are typically derived from polycarboxy compounds such as thepolyacrylates. When using glycerol as the crosslinking agent, thehydroxy groups of the glycerol typically react with the carboxy groupsof the polymers present in the absorbent particles by an esterificationreaction. The crosslinked, ester bond formed by glycerol occurs not onlyat the surface of the absorbent particles, but also inside particles.This is due to the fact that glycerol is a nonionic, relatively smallmolecule that can penetrate inside the absorbent particles. Theresulting internal crosslinking leads to a lower absorbent capacity forthe bonded particles of the aggregate macrostructures.

Moreover, the crosslinking reaction between the hydroxy groups of theglycerol and the carboxy groups of the polymers present in the absorbentparticles is relatively slow. Indeed, the glycerol treated absorbentparticles are typically cured at 200° C. for 50 minutes. This providesrelatively brittle sheets of bonded absorbent particles that are moredifficult to handle, especially in making the ultimately desiredabsorbent structures. Accordingly, these brittle sheets need to betreated with a plasticizer, such as a mixture of water and glycerol, tomake them relatively flexible and thus easier to handle in manufacturingabsorbent structures.

Accordingly, it would be desirable to be able to make such aggregatemacrostructures of bonded absorbent particles using a crosslinking agentthat: (1) reacts rapidly with the carboxy groups of the polymer presentin the absorbent particles and primarily at the surface thereof tominimize absorbency effects; (2) provides improved absorbency andmechanical (tensile) properties for the aggregate macrostructures; (3)provides flexible sheets of such aggregate macrostructures that can beeasily made into absorbent structures used in diapers, adultincontinence pads, sanitary napkins and the like; and (4) does notnecessarily require organic solvents such as isopropanol.

DISCLOSURE OF THE INVENTION

The present invention relates to improved porous, absorbent,macrostructures that comprise interparticle bonded aggregates. Theseaggregates comprise a multiplicity of precursor absorbent particlesbonded to each other at the surface thereof, the particles comprising asubstantially water-insoluble, absorbent hydrogel-forming, polymermaterial having anionic functional groups. These aggregates furthercomprise a cationic, preferably polymeric, amino-epichlorohydrin adductreacted with the absorbent polymer material at the surface of theprecursor particles and in an amount sufficient to effective surfacecrosslinking. These aggregates also have pores between adjacentprecursor particles, the pores being interconnected byintercommunicating channels so as to form a liquid permeablemacrostructure, the circumscribed dry volume of the macrostructure beinggreater than about 0,008 mm³.

The present invention further relates to a method for making such porousabsorbent macrostructures by providing a multiplicity of the precursorabsorbent particles that are then treated with a sufficient amount ofthe cationic, preferably polymeric, amino-epichlorohydrin adduct. Thetreated precursor particles are then physically associated to formaggregates and the adduct reacted with the absorbent polymer material ofthe precursor particles so as to cause effective surface crosslinking.The porous, absorbent macrostructures obtained are useful, alone, or incombination with other absorbent materials, in absorbent structures forvarious absorbent articles, including diapers, adult incontinence pads,sanitary napkins, and the like.

The porous absorbent macrostructures of the present invention, andmethod for making same, provide a number of significant advantages overprior porous absorbent macrostructures made with nonionic crosslinkingagents, in particular glycerol. The use of cationic, preferablypolymeric, amino-epichlorohydrin adducts as the crosslinking agentaccording to the present invention improves the cure rate and enhancesthe absorbent capacity of the particles by reducing or eliminatinginnerparticle crosslinking. This is due to the fact that these adducts,especially the polymeric resin versions, being relatively large,cationic molecules, are unable to penetrate inside the absorbentparticles. In addition, the cationic functional (e.g., azetedinium)groups of these adducts are believed to react very rapidly with theartionic, typically carboxy, functional groups of the polymer materialcomprising the absorbent particles, even at ambient room temperature,e.g., at 18°-25° C.). As a result, lower levels of crosslinking agentare required, e.g., as low as 1% by weight of the absorbent particles,versus typically 4% by weight for glycerol as the crosslinking agent.

Use of these cationic, preferably polymeric, amino-epichlorohydrinadducts provides other significant advantages over porous absorbentmacrostructures made with glycerol as the crosslinking agent. The porousabsorbent macrostructures of the present invention have improvedabsorbency and mechanical (tensile) properties. Unlikeglycerol-crosslinked absorbent macrostructures, flexible absorbentmacrostructures (e.g., sheets) according to the present invention can bemade by an essentially one-step process without the need of subsequenttreatment with a plasticizer (e.g., adding a mixture of water andglycerol). In addition, organic solvents such as isopropanol are notrequired in making absorbent macrostructures according to the presentinvention.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a photomicrograph (magnification 34.9×) of a section of aporous, absorbent macrostructure according to the present invention;

FIG. 2 is an enlarged portion (magnification 75×) of the macrostructureshown in FIG. 1;

FIG. 3 is a further enlarged portion (magnification 200×) of themacrostructure shown in FIG. 2;

FIG. 4 is a further enlarged portion (magnification 400×) of themacrostructure shown in FIG. 3;

FIG. 5 is a perspective view of a disposable diaper embodiment accordingto the present invention wherein portions of the topsheet have beencut-away to more clearly show the underlying absorbent core (anembodiment of an absorbent member according to the present invention) ofthe diaper wherein the absorbent member comprises a porous, absorbentmacrostructure according to the present invention;

FIG. 6 is a cross-sectional view of the absorbent core of the diapershown in FIG. 5 taken along sectional line 6--6 of FIG. 8;

FIG. 7 is a perspective view of a disposable diaper embodiment accordingto the present invention wherein portions of the topsheet have been cutaway to more clearly show an alternative dual-layer absorbent coreembodiment;

FIG. 8 is a blown-apart view of the components of a diaper structure,one of the components being an alternative dual-layer absorbent corewhere the absorbent macrostructure is in the form of a plurality ofstrips; and

FIG. 9 is a simplified perspective view of an apparatus for makingabsorbent macrostructures of the present invention in the form ofsheets.

DETAILED DESCRIPTION OF THE INVENTION A. Porous AbsorbentMacrostructures

Porous, absorbent macrostructures according to the present invention arestructures capable of absorbing large quantities of liquids such aswater and/or body exudates (e.g., urine or menses) and then retainingsuch liquids under moderate pressures. Because of the particulate natureof the precursor particles, the macrostructure has pores betweenadjacent precursor particles. These pores are interconnected byintercommunicating channels such that the macrostructure is liquidpermeable (i.e., has capillary transport channels).

Due to the bonds formed between the precursor particles, the resultantaggregate macrostructure has improved structural integrity, increasedliquid acquisition and distribution rates, and minimal gel-blockingcharacteristics. It has been found that when the macrostructure iscontacted with liquids, the macrostructure swells generallyisotropically even under moderate confining pressures, absorbs suchliquids into the pores between the precursor particles, and then imbibessuch liquids into the particles. The isotropic swelling of themacrostructure allows the precursor particles and the pores to maintaintheir relative geometry and spatial relationships even when swollen.Thus, the macrostructures are relatively "fluid stable" in that theprecursor particles do not dissociate from each other, therebyminimizing the incidence of gel blocking and allowing the capillarychannels to be maintained and enlarged when swollen so that themacrostructure can acquire and transport subsequent loadings of liquid,even excess liquid.

As used herein, the term "macrostructure" means a structure having acircumscribed volume when substantially dry (i.e., circumscribed dryvolume) of at least about 0.008 mm³, preferably at least about 10.0 mm³,more preferably at least about 100 mm³, most preferably at least about500 mm³. Typically, the macrostructures of the present invention willhave a circumscribed dry volume much greater than about 500 mm³. Inpreferred embodiments of the present invention, the macrostructures havea circumscribed dry volume of between about 1000 mm³ and about 100,000mm³.

While the macrostructures of the present invention can have a number ofshapes and sizes, they are typically in the form of sheets, films,cylinders, blocks, spheres, fibers, filaments, or other shaped elements.The macrostructures will generally have a thickness or diameter betweenabout 0.2 mm and about 10.0 mm. Preferably for use in absorbentproducts, the macrostructures are in the form of a sheet. The term"sheet" as used herein describes macrostructures having a thickness atleast about 0.2 mm. The sheets will preferably have a thickness betweenabout 0.5 mm and about 10 mm, typically from about 1 mm to about 3 mm.

As shown in FIGS. 1 through 4, the porous, absorbent macrostructures ofthe present invention comprise interparticle bonded aggregates. Theseinterparticle bonded aggregates usually comprise about 8 or morepreviously independent precursor particles. For preferred circumscribeddry volumes and sizes of the individual precursor particles used herein,these interparticle bonded aggregates typically are formed from about100,000 or more individual precursor particles. These individualprecursor particles can comprise granules, pulverulents, spheres,flakes, fibers, aggregates or agglomerates.

As can be especially seen in FIGS. 1 and 2, the individual precursorparticles can have a variety of shapes, such as cubic, rod-like,polyhedral, spherical, rounded, angular, irregular, randomly-sizedirregular shapes, e.g., pulverulent products of grinding or pulverizingsteps, or shapes having a large greatest dimension/smallest dimensionratio so as to be needle-like, flake-like, or fiber-like.

As particularly shown in FIGS. 3 and 4, the interparticle bondedaggregate comprising the macrostructures of the present invention areformed, in essence, by the joining or adhering together of adjacentparticles. The adhesive agent is essentially the polymeric material thatis present in the surface of these particles. When these precursorparticles are treated and physically associated as described hereafter,the polymer material present in the surface of these particles issufficiently plastic and cohesive (e.g., sticky) such that adjacentparticles are adhered together, typically as discrete linking portionsbetween the particles. The crosslinking reaction between theamino-epichlorohydrin adduct and the polymer material of the particlesthen sets this adhered structure such that the particles in theaggregate remain cohesively bonded together.

B. Absorbent Precursor Particles

The macrostructures of the present invention are formed from polymermaterials capable of absorbing large quantities of liquids. (Such.polymer materials are commonly referred to as "hydrogel","hydrocolloid", or "superabsorbent" materials.) The macrostructurespreferably comprise substantially water-insoluble, absorbenthydrogel-forming, polymer material. The specific polymer materials willbe discussed herein with respect to those forming the precursorparticles.

Although the precursor particles can have a size varying over a widerange, specific particle size distributions and sizes are preferred. Forpurposes of the present invention, particle size is defined forprecursor particles that do not have a large greatest dimension/smallestdimension ratio such as fibers (e.g., granules, flakes, or pulverulents)as the dimension of a precursor particle which is determined by sievesize analysis. Thus, for example, a precursor particle that is retainedon a standard #30 sieve with 600 micron openings is considered to have aparticle size greater than 600 microns, a precursor particle that passesthrough the #30 sieve with 600 micron openings and is retained on astandard #35 sieve with 500 micron openings is considered to have aparticle size between 500 and 600 microns, and a precursor particle thatpasses through a #35 sieve with 500 micron openings is considered tohave a particle size less than 500 microns. In preferred embodiments ofthe present invention, the precursor particles will generally range insize from about 1 micron to about 2000 microns, more preferably fromabout 20 microns to about 1000 microns.

Further, for purposes of this invention, the mass average particle sizeof the precursor particles is important in determining thecharacteristics and properties of the resultant macrostructures. Themass average particle size of a given sample of precursor particles isdefined as the particle size which is the average particle size of thesample on a mass basis. A method for determining the mass averageparticle size of a sample is described hereinafter in the Test Methodssection. The mass average particle size of the precursor particles willgenerally be from about 20 microns to about 1500 microns, morepreferably from about 50 microns to about 1000 microns. In preferredembodiments of the present invention, the precursor particles have amass average particle size less than about 1000 microns, more preferablyless than about 600 microns, most preferably less than about 500microns. In especially preferred embodiments of the present invention,the mass average particle size of the precursor particles is relativelysmall (i.e. the precursor particles are fines). In these embodiments,the mass average particle size of the precursor particles is less thanabout 300 microns, more preferably less than about 180 microns. In anexemplary embodiment, at least about 95% by weight of the precursorparticles have a particle size between about 150 microns and about 300microns. In an alternative embodiment,. at least about 95% by weight ofthe precursor particles have a particle size between about 90 micronsand about 180 microns. Narrow precursor particle size distributions arepreferred because they result in a higher porosity macrostructure due tothe higher void fraction when densified versus broader precursorparticle size distributions with equivalent mass average particle sizes.

The particle size of materials having a large greatestdimension/smallest dimension such as fibers is typically defined bytheir largest dimension. For example, if absorbent, polymeric fibers(i.e. superabsorbent fibers) are used in the macrostructures of thepresent invention, the length of the fibers is used to define the"particle size." (The denier and/or the diameter of the fibers can alsobe specified.) In exemplary embodiments of the present invention, thefibers have a length greater than about 5 mm, preferably between about10 mm and about 100 mm, more preferably between about 10 mm and about 50mm.

The precursor particles comprise substantially water-insoluble,absorbent hydrogel-forming, polymer material having a multiplicity ofanionic, functional groups, such as sulfonic acid, and more typicallycarboxy, groups. Examples of polymer materials suitable for use as theprecursor particles herein include those which are prepared frompolymerizable, unsaturated, acid-containing monomers. Thus, suchmonomers include the olefinically unsaturated acids and anhydrides whichcontain at least one carbon to carbon olefinic double bond. Morespecifically, these monomers can be selected from olefinicallyunsaturated carboxylic acids and acid anhydrides, olefinicallyunsaturated sulfonic acids, and mixtures thereof.

Some non-acid monomers can also be included, usually minor amounts, inpreparing the precursor particles herein. Such non-acid monomers caninclude, for example, the water-soluble or water-dispersible esters ofthe acid-containing monomers, as well as monomers which contain nocarboxylic or sulfonic acid groups at all. Optional non-acid monomerscan thus include monomers containing the following types of functionalgroups: carboxylic acid or sulfonic acid esters, hydroxyl groups,amide-groups, amino groups, nitrile groups and quaternary ammomium saltgroups. These non-acid monomers are well-known materials and aredescribed in greater detail, for example, in U.S. Pat. No. 4,076,663(Masuda et al), issued Feb. 28, 1978, and in U.S. Pat. No. 4,062,817(Westerman), issued Dec. 13, 1977, both of which are incorporated byreference.

Olefinically unsaturated carboxylic acid and carboxylic acid anhydridemonomers include the acrylic acids typified by acrylic acid itself,methacrylic acid, ethacrylic acid, α-chloroacrylic acid, α-cyanoacrylicacid, β-methylacrylic acid (crotonic acid), α-phenylacrylic acid,β-acryloxypropionic acid, sorbic acid, α-chlorosorbic acid, angelicacid, cinnamic acid, p-chlorocinnamic acid, β-sterylacrylic acid,itaconic acid, citroconic acid, mesaconic acid, glutaconic acid,aconitic acid, maleic acid, fumaric acid, tricarboxyethylene and maleicacid anhydride.

Olefinically unsaturated sulfonic acid monomers include aliphatic oraromatic vinyl sulfonic acids such as vinylsulfonic acid, allyl sulfonicacid, vinyl toluene sulfonic acid and styrene sulfonic acid; acrylic andmethacrylic sulfonic acid such as sulfoethyl acrylate, sulfoethylmethacrylate, sulfopropyl acrylate, sulfopropyl methacrylate, 2-hydroxy-3-methacryloxypropyl sulfonic acid and2-acrylamide-2-methylpropane sulfonic acid.

Preferred polymer materials for use in the present invention containcarboxy groups. These polymers include hydrolyzed starch-acrylonitrilegraft copolymers, partially neutralized starch-acrylonitrile graftcopolymers, starch-acrylic acid graft copolymers, partially neutralizedstarch-acrylic acid graft copolymers, saponified vinyl acetate-acrylicester copolymers, hydrolyzed acrylonitrile or acrylamide copolymers,slightly network crosslinked polymers of any of the foregoingcopolymers, partially neutralized polyacrylic acid, and slightly networkcrosslinked polymers of partially neutralized polyacrylic acid. Thesepolymers can be used either solely or in the form of a mixture of two ormore different polymers. Examples of these polymer materials aredisclosed in U.S. Pat. Nos. 3,661,875, 4,076,663, 4,093,776, 4,666,983,and 4,734,478.

Most preferred polymer materials for use in making the precursorparticles are slightly network crosslinked polymers of partiallyneutralized polyacrylic acids and starch derivatives thereof. Mostpreferably, the precursor particles comprise from about 50 to about 95%,preferably about 75%, neutralized, slightly network crosslinked,polyacrylic acid (i.e. poly (sodium acrylate/acrylic acid)).

As described above, the precursor particles are preferably made frompolymer materials that are slightly network crosslinked. Networkcrosslinking serves to render the polymer materials from which theprecursor particles are made substantially water-insoluble and, in part,determines the absorptive capacity and extractable polymer contentcharacteristics of the precursor particles and the resultantmacrostructures. Processes for network crosslinking the, polymers andtypical network crosslinking agents are described in greater detail inthe hereinbefore-referenced U.S. Pat. No. 4,076,663.

The individual precursor particles can be formed in any conventionalmanner. Typical and preferred processes for producing, the individualprecursor particles are described in U.S. Pat. No. Re. 32,649 (Brandt etal), issued Apr. 19, 1988, U.S. Pat. No. 4,666,983 (Tsubakimoto et al),issued May 19, 1987, and U.S. Pat. No. 4,625,001 (Tsubakimoto et al),issued Nov. 25, 1986, all of which are incorporated by reference.

Preferred methods for forming the precursor particles are those thatinvolve aqueous solution or other solution polymerization methods. Asdescribed in the above-referenced U.S. Pat. No. 32,649, aqueous solutionpolymerization involves the use of an aqueous reaction mixture to carryout polymerization to form the precursor particles. The aqueous reactionmixture is then subjected to polymerization conditions which aresufficient to produce in the mixture, substantially water-insoluble,slightly network crosslinked polymer material. The mass of polymermaterial thereby formed is then pulverized or chopped to form theindividual precursor particles.

More specifically, the aqueous solution polymerization method forproducing the individual precursor particles comprises the preparationof an aqueous reaction mixture in which to carry out polymerization toform the desired precursor particles. One element of such a reactionmixture is the acid group-containing monomer material which will formthe "backbone" of the precursor particles to be produced. The reactionmixture will generally comprise about 100 parts by weight of the monomermaterial. Another component of the aqueous reaction mixture comprises anetwork crosslinking agent. Network crosslinking agents useful informing the precursor particles are described in more detail in theabove-referenced U.S. Pat. No. Re. 32,649, U.S. Pat. No. 4,666,983, andU.S. Pat. No. 4,625,001. The network crosslinking agent will generallybe present in the aqueous reaction mixture in an amount of from about0,001 mole percent to about 5 mole percent based on the total moles ofmonomer present in the aqueous mixture (about 0.01 to about 20 parts byweight, based on 100 parts by weight of the monomer material). Anoptional component of the aqueous reaction mixture comprises a freeradical initiator including, for example, peroxygen compounds such assodium, potassium, and ammonium persulfates, caprylyl peroxide, benzoylperoxide, hydrogen peroxide, cumene hydroperoxides, tertiary butyldiperphthalate, tertiary butyl perbenzoate, sodium peracetate, sodiumpercarbonate, and the like. Other optional components of the aqueousreaction mixture comprise the various non-acidic co-monomer materialsincluding esters of the essential unsaturated acidic functionalgroup-containing monomers or other co-monomers containing no carboxylicor sulfonic acid functionalities at all.

The aqueous reaction mixture is subjected to polymerization conditionswhich are sufficient to produce in the mixture substantiallywater-insoluble, absorbent, hydrogel-forming, slightly networkcrosslinked polymer materials. The polymerization conditions are alsodiscussed in more detail in the three above-referenced patents. Suchpolymerization conditions generally involve heating (thermal activationtechniques) to a polymerization temperature from about 0° C. to about100° C., more preferably from about 5° C. to about 40° C. Polymerizationconditions under which the aqueous reaction mixture is maintained canalso include, for example, subjecting the reaction mixture, or portionsthereof, to any conventional form of polymerization activatingirradiation. Radioactive, electronic, ultraviolet, or electromagneticradiation are alternative conventional polymerization techniques.

The acid functional groups of the polymer materials formed in theaqueous reaction mixture are also preferably neutralized. Neutralizationcan be carried out in any conventional manner which results in at leastabout 25 mole percent, and more preferably at least about 50 molepercent, of the total monomer utilized to form the polymer materialbeing acid group-containing monomers that are neutralized with asalt-forming cation. Such salt-forming cations include, for example,alkali metals, ammonium, substituted ammonium and amines as discussed infurther detail in the above-references U.S. Pat. No. Re. 32,649.

While it is preferred that the precursor particles be manufactured usingan aqueous solution polymerization process, it is also possible to carryout the polymerization process using multi-phase polymerizationprocessing techniques such as inverse emulsion polymerization or inversesuspension polymerization procedures. In the inverse emulsionpolymerization or inverse suspension polymerization procedures, theaqueous reaction mixture as hereinbefore described is suspended in theform of tiny droplets in a matrix of a water-immiscible, inert organicsolvent such as cyclohexane. The resultant precursor particles aregenerally spherical in shape. Inverse suspension polymerizationprocedures are described in greater detail in U.S. Pat. No. 4,340,706(Obaysashi et al), issued Jul. 20, 1982, U.S. Pat. No. 4,506,052(Flesher et al), issued Mar. 19, 1985, and U.S. Pat. No. 4,735,987(Morita et al), issued Apr. 5, 1988, all of which are incorporated byreference.

In preferred embodiments of the present invention, the precursorparticles used to form the bonded particle aggregates are substantiallydry. The term "substantially dry" is used herein to mean that theprecursor particles have a liquid content, typically water or othersolution content, less than about 50%, preferably less than about 20%,more preferably less than about 10%, by weight of the precursorparticles. In general, the liquid content of the precursor particles isin the range of from about 0.01% to about 5% by weight of the precursorparticles. The individual precursor particles can be dried by anyconventional method such as by heating. Alternatively, when theprecursor particles are formed using an aqueous reaction mixture, watercan be removed from the reaction mixture by azeotropic distillation. Thepolymer-containing aqueous reaction mixture can also be treated with adewatering solvent such as methanol. Combinations of these dryingprocedures can also be used. The dewatered mass of polymer material canthen be chopped or pulverized to form substantially dry precursorparticles of substantially water-insoluble, absorbent, hydrogel-forming,polymer material.

Preferred precursor particles of the present invention are those whichexhibit a high absorptive capacity so that the resultant macrostructureformed from such precursor particles also has a high absorptivecapacity. Absorptive capacity refers to the capacity of a given polymermaterial to absorb liquids with which it comes into contact. Absorptivecapacity can vary significantly with the nature of the liquid beingabsorbed and with the manner in which the liquid contacts the polymermaterial. For purposes of this invention, Absorptive Capacity is definedin terms of the amount of Synthetic Urine (as hereinafter defined)absorbed by any given polymer material in terms of grams of SyntheticUrine per gram of polymer material in a procedure hereinafter defined inthe Test Methods section. Preferred precursor particles of the presentinvention are those which have an Absorptive Capacity of at least about20 grams, more preferably at least about 25 grams, of Synthetic Urineper gram of polymer material. Typically, the polymer materials of theprecursor particles herein have an Absorptive Capacity of from about 20grams to about 70 grams of Synthetic Urine per gram of polymer material.Precursor particles having this relatively high absorptive capacitycharacteristic produce macrostructures that are especially useful inabsorbent products, absorbent members, and absorbent articles since theresultant macrostructures formed from such precursor particles can, bydefinition, hold desirably high amounts of discharged body exudates suchas urine.

While all of the precursor particles are preferably formed from the samepolymer material with the same properties, this need not be the case.For example, some precursor particles can comprise a starch-acrylic acidgraft copolymer while other precursor particles can comprise a slightlynetwork crosslinked polymer of partially neutralized polyacrylic acid.Further, the precursor particles can vary in size, shape, absorptivecapacity, or any other property or characteristic. In a preferredembodiment of the present invention, the precursor particles consistessentially of slightly network crosslinked polymers of partiallyneutralized polyacrylic acid, each precursor particle having similarproperties.

C. Cationic Amino-Epichlorohydrin Adducts

A key component of the interparticle bonded aggregates that comprise theporous macrostructures of the present invention is an adduct ofepichlorohydrin with certain types of monomeric or polymeric amines.These amino-epichlorohydrin adducts react with the polymer material ofthe absorbent precursor particles, and in particular the anionic,typically carboxy, functional groups of these polymer materials to forma covalent, ester-type bond. In other words, the amino-epichlorohydrinadduct serves to crosslink the polymer material present in the absorbentprecursor particles. (The portions of the absorbent particle containingpolymer material that has been effectively crosslinked with theamino-epichlorohydrin adduct swell less in the presence of aqueous bodyfluids relative to the other uncrosslinked portions of the particle.)

It is believed that these reacted amino-epichlorohydrin adductsprimarily provide crosslinking at the surface of the absorbent precursorparticles. This is due to the fact that these adducts, and especiallythe polymeric resin versions of these adducts, are relatively large,cationic molecules. As a result, they are unable to penetrate inside theabsorbent particles, and therefore can only react with polymer materialat the surface thereof. In addition, the cationic functional groups(e.g., azetedinium groups) of these adducts, particularly polymericresin versions, are believed to react very rapidly with the artionic,typically carboxy, functional groups of the polymer material of theabsorbent particles, even at room temperature (e.g., at from about 18°to about 25° C.). As a result, fairly modest levels (e.g., as low asabout 1% by weight of the particles) of these amino-epichlorohydrinadducts are required to provide effective surface crosslinking of thepolymer material present in the absorbent precursor particles.

As used herein, "cationic amino-epichlorohydrin adduct" refers to thereaction product between epichlorohydrin and a monomeric or polymericamine such that the resulting reaction product has at least two cationicfunctional groups. These adducts can be in the form of monomericcompounds (e.g., the reaction product of epichlorohydrin and ethylenediamine), or can be in polymeric form (e.g., the reaction productbetween epichlorohydrin, and polyamide-polyamines orpolyethyleneimines). The polymeric versions of these cationicamino-epichlorohydrin adducts are typically referred to as "resins."

One type of amino compound which can be reacted with epichlorohydrin toform adducts useful in the present invention comprises monomeric di-,tri- and higher amines having primary or secondary amino groups in theirstructures. Examples of useful diamines of this type includebis-2-aminoethyl ether, N,N-dimethylethylenediamine, piperazine, andethylenediamine. Examples of useful triamines of this type includeN-aminoethyl piperazine, and dialkylene triamines such asdiethylenetriamine, and dipropylenetriamine.

Such amine materials are reacted with epichlorohydrin to form thecationic amino-epichlorohydrin adducts useful as crosslinking agentsherein. Preparation of these adducts, as well as a more completedescription of the adducts themselves, can be found in U.S. Pat. No.4,310,593 (Gross), issued Jan. 12, 1982, and in Ross et al, J. OrganicChemistry, Vol. 29, pp. 824-826 (1964). Both of these documents areincorporated by reference.

In addition to monomeric amines, polymeric amines such aspolyethyleneimines can also be used as the amino compound. Aparticularly desirable amino compound which can be reacted withepichlorohydrin to form preferred cationic polymeric adduct resinsuseful herein comprise certain polyamide-polyamines derived frompolyalkylene polyamines and saturated C₃ -C₁₀ dibasic carboxylic acids.Epichlorohydrin/polyamide-polyamine adducts of this kind arewater-soluble, thermosetting cationic polymers which are well known inthe art as wet strength resins for paper products.

In the preparation of polyamide-polyamines used to form this preferredclass of cationic polymeric resins, a dicarboxylic acid is first reactedwith a polyalkylene-polyamine, preferably in aqueous solution, underconditions such as to produce a water-soluble, long chain polyamidecontaining the recurring groups --NH(C_(n) H_(2n) HN)_(x) --CORCO--where n and x are each 2 or more and R is the C₁ to C₈ alkylene group ofthe dicarboxylic acid.

A variety of polyalkylene polyamines including polyethylene polyamines,polypropylene polyamines, polybutylene polyamines and so on can beemployed to prepare the polyamide-polyamine, of which the polyethylenepolyamines represent an economically preferred class. More specifically,preferred polyalkylene polyamines used to prepare the cationic polymericresins herein are polyamines containing two primary amine groups and atleast one secondary amine group in which the nitrogen atoms are linkedtogether by groups of the formula --C_(n) H_(2n) -- where n is a smallinteger greater than unity and the number of such groups in the moleculeranges from two up to about eight and preferably up to about four. Thenitrogen atoms can be attached to adjacent carbon atoms in the group--C_(n) H_(2n) -- or to carbon atoms further apart, but not to the samecarbon atom. Also contemplated is the use of such polyamines asdiethylenetriamine, triethylenetetramine, tetraethylenepentamine,dipropylenetriamine, and the like, which can be obtained in reasonablypure form. Of all the foregoing, the most preferred are the polyethylenepolyamines containing from two to four ethylene groups, two primaryamine groups, and from one to three secondary amine groups.

Also contemplated for use herein are polyamine precursor materialscontaining at least three amino groups with at least one of these groupsbeing a tertiary amino group. Suitable polyamines of this type includemethyl bis(3-aminopropyl)amine, methyl bis(2-aminoethyl)amine,N-(2-aminoethyl)piperazine, 4,7-dimethyltriethylenetetramine and thelike.

The dicarboxylic acids which can be reacted with the foregoingpolyamines to form the polyamide-polyamine precursors of the preferredcationic polymeric resins useful herein comprise the saturated aliphaticC₃ -C₁₀ dicarboxylic acids. More preferred are those containing from 3to 8 carbon atoms, such as malonic, succinic, glutaric, adipic, and soon, together with diglycolic acid. Of these, diglycolic acid and thesaturated aliphatic dicarboxylic acids having from 4 to 6 carbon atomsin the molecule, namely, succinic, glutaric and adipic are mostpreferred. Blends of two or more of these dicarboxylic acids can also beused, as well as blends of one or more of these with higher saturatedaliphatic dicarboxylic acids such as azelaic and sebacic, as long as theresulting long chain polyamide-polyamine is water-soluble or at leastwater-dispersible.

The polyamide-polyamine materials prepared from the foregoing polyaminesand dicarboxylic acids are reacted with epichlorohydrin to form thecationic polymeric amino-epichlorohydrin resins preferred for use hereinas the crosslinking agent. Preparation of such materials is describe ingreater detail in U.S. Pat. No. 2,926,116 (Keim), issued Feb. 23, 1960,U.S. Pat. No. 2,926,154 (Keim), issued Feb. 23, 1960, and U.S. Pat. No.3,332,901 (Keim), issued Jul. 25, 1967, all of which are incorporated byreference.

The cationic polyamide-polyamine-epichlorohydrin resins preferred foruse herein as crosslinking agents are commercially marketed by HerculesInc. under the trade name Kymene®. Especially useful are Kymene® 557H,Kymene® 557LX and Kymene® 557 Plus, which are the epichlorohydrinadducts of polyamide-polyamines which are the reaction products ofdiethylenetriamine and adipic acid. They are typically marketed in theform of aqueous solutions of the cationic resin material containing fromabout 10% to about 33% by weight of the resin active.

D. Preparation of Interparticle Bonded Aggregates and Macrostructures

In preparing the interparticle bonded aggregates that comprise theporous, absorbent macrostructures of the present invention, theabsorbent precursor particles are treated with an sufficient amount ofthe cationic amino-epichlorohydrin adduct to react with the polymermaterial at the surface of the particles so as to cause effectivecrosslinking, i.e., the crosslinked surface of the particle swells lessin the presence of aqueous body fluids relative to the uncrosslinkedportions. What constitutes "a sufficient amount" of the adduct dependsupon a number of factors, including the particular absorbent precursorparticles treated, the particular amino-epichlorohydrin adduct used, theparticular effects desired in forming the interparticle bondedaggregate, and like factors. In the case of monomericamino-epichlorohydrin adducts, such as a piperazine-epichlorohydrinadducts, the amount of adduct used can be in the range of from about 0.1to about 3 parts by weight, preferably from about 0.5 to about 1.5 partsby weight, most preferably from about 0.8 to about 1.2 parts by weight,per 100 parts by weight of the absorbent precursor particles. In thecase of preferred polymeric amino-epichlorohydrin resins, such asKymene® 557H, 557LX or Plus, the amount of resin used can be from about0.1 to about 5 parts by weight, preferably from about 0.5 to about 2.5parts by weight, most preferably from about 1 to about 2 parts byweight, per 100 parts by weight of the absorbent precursor particles.

Besides the absorbent precursor particles and the cationicamino-epichlorohydrin adduct, other components or agents can be used asaids in preparing the interparticle bonded aggregates. For example,water is typically used with the adduct to form an aqueous treatmentsolution thereof. Water promotes the uniform dispersion of the adduct onthe surface of the precursor particles and causes permeation of theadduct into the surface regions of these particles. Water also promotesa stronger physical association between the treated precursor particles,providing greater integrity of the resultant interparticle bondedcrosslinked aggregates. In the present invention, water is used in anamount of less than about 25 parts by weight (i.e. from 0 to about 25parts by weight), preferably in the range of from about 3 to about 15parts by weight, more preferably in the range of from about 5 to about10 parts by weight, per 100 parts by weight of the precursor particles.The actual amount of water used can vary depending upon the type ofadduct used, the type of polymer material used in forming the precursorparticles, the particle size of these precursor particles, the inclusionof other optional components (e.g., glycerol) and like factors.

Although not absolutely necessary, organic solvents can be used, usuallyto promote uniform dispersion of the cationic amino-epichlorohydrinadduct onto the surface of the precursor particles. These organicsolvents are typically hydrophilic, and can include lower alcohols suchas methanol and ethanol; amides such as N,N-dimethylformamide andN,N-diethylformamide; and sulfoxides such as dimethylsulfoxide. If ahydrophilic solvent is used, it is in an amount of less than about 20parts by weight (i.e. from 0 to about 20 parts by weight), preferably inthe range of from about 5 to about 15 parts by weight, more preferablyin the range of from about 8 to about 12 parts by weight, per 100 partsby weight of the precursor particles. The actual amount of hydrophilicsolvent used can vary depending upon the adduct used, the polymermaterial used forming the precursor particles, the particle size ofthese precursor particles and like factors.

As previously noted, the use of hydrophilic organic solvents is notnecessarily required in preparing bonded particle aggregates of thepresent invention. Indeed, it can be desirable to avoid the use of suchorganic solvents. Such solvents typically need to be removed from theaggregate before it is suitable for its intended use. The removal oforganic solvents is frequently an energy and process intensive, and addsadditional processing costs. Some hydrophilic solvents, such asisoproponal or t-butanol, can cause the amino-epichlorohydrin adduct toprecipitate out of solution and are therefore undesirable for thisreason. Indeed, the only solvents typically used in preparing the bondedparticle aggregates of the present invention are the lower alcohols suchas methanol and ethanol that are not too energy or process intensive toremove, and do not cause the amino-epichlorohydrin adduct to precipitateout of aqueous solution.

Other optional components can also be used with the cationicamino-epichlorohydrin adduct, and especially aqueous treatment solutionsthereof. It is particularly preferred that the treatment solutioncomprising the cationic amino-epichlorohydrin adduct include aplasticizer, especially when the treated precursor particles are ambienttemperature cured as described hereafter. In the absence of aplasticizer, the treated precursor particles, when formed into theinterparticle bonded aggregates, can be relatively brittle, and thusmore difficult to handle, especially in making the ultimately desiredabsorbent structures. Inclusion of a plasticizer in the treatmentsolution insures that the resulting interparticle bonded aggregates(when ambient temperature cured) form relatively flexible porous,absorbent macrostructures, particularly flexible, porous, absorbentsheets of the interparticle bonded aggregates. These flexible sheets arerelatively easy to handle in making the ultimately desired absorbentstructures.

Suitable plasticizers include water, alone or in combination with othercomponents such as glycerol, propylene glycol (i.e. 1,2-propanediol),1,3-propanediol, ethylene glycol, sorbitol, sucrose, polymeric solutionssuch as those involving polyvinyl alcohol, ester precursors of polyvinylalcohol, or polyethylene glycol, or mixtures thereof. These othercomponents in the plasticizer, such as glycerol, are believed to act ashumectants, coplasticizers or both, with water being the primaryplasticizer. The preferred plasticizer for use in the present inventionis a mixture of glycerol and water, particularly when included as partof an aqueous treatment solution of the cationic amino-epichlorohydrinadduct, in a weight ratio of glycerol to water of from about 0.5:1 toabout 2:1, preferably from about 0.8:1 to about 1.7:1.

The actual amount of plasticizer used can vary depending upon theparticular plasticizer used, the type of polymer material used informing the precursor particles, and the particular flexibility effectsdesired from the plasticizer. Typically, the plasticizer is used in anamount of from about 5 to about 100 parts by weight, preferably fromabout 5 to about 60 parts by weight, more preferably from about 10 toabout 30 parts by weight, most preferably from about 15 to about 20parts by weight, per 100 parts by weight of the precursor particles.

In the method of the present invention, the absorbent precursorparticles can be treated with the cationic amino-epichlorohydrin adduct,typically an aqueous solution thereof, by any of a variety oftechniques. These include any method for applying solutions tomaterials, including coating, dumping, pouring, dropping, spraying,atomizing, condensing, or immersing the absorbent precursor particleswith the cationic amino-epichlorohydrin adduct, or solution thereof. Asused herein, the term "applied" means that at least a portion of thesurface area of at least some of the precursor particles to be bondedtogether has an effective amount of the adduct on it to cause surfacecrosslinking. In other words, the cationic adduct can be applied ontosome of the precursor particles, all of the precursor particles, aportion of the surface of some or all of the precursor particles, or theentire surface of some or all of the precursor particles. Preferably,the adduct is coated onto the entire surface of most, preferably all, ofthe absorbent precursor particles so as to enhance the efficiency,strength, and density of the interparticle bonds between the precursorparticles, as well as the desired surface crosslinking of the polymermaterial in the surface of these precursor particles.

In an embodiment of the method of the present invention, after thetreatment solution has been applied onto the precursor particles, thetreated precursor particles are mixed or layered together by any of anumber of mixing or layering techniques to insure that the precursorparticles are thoroughly coated with the treatment solution. Because theprecursor particles are thoroughly coated with the treatment solution,the efficiency, strength, and density of the bonds between the precursorparticles is enhanced, as well as surface crosslinking resulting fromthe reaction of the cationic adduct with the polymer material formingthe precursor particles. This mixing can be accomplished using varioustechniques and apparatus, including various mixers or kneaders, as areknown in the art.

Before, during, or after applying the treatment solution, the precursorparticles are physically associated together to form an aggregatemacrostructure. The term "physically associated" is used herein to meanthat the precursor particles are brought together and remain in contactwith each other as component parts in any of a number of various waysand spatial relationships so as to form a single unit (an aggregatemacrostructure).

The precursor particles are preferably physically associated together byapplying an associating agent onto the precursor particles andphysically contacting the precursor particles at at least the portion ofthe surface of the precursor particles having the associating agentapplied thereto. Preferred associating agents cause the polymer materialof the precursor particles, when brought together, to adhere together bythe action of fluid surface tension forces and/or the entanglement ofpolymer chains due to external swelling. Associating agents useful inthe present invention include hydrophilic organic solvents, typicallylow molecular Weight alcohols such as methanol or ethanol; water; amixture of hydrophilic organic solvents and water; the cationicamino-epichlorohydrin adducts previously described, or mixtures thereof.Preferred associating agents are water, methanol, ethanol, cationicpolymeric amino-epichlorohydrin resins such as Kymene® 557H, or 557LX orPlus, or mixtures thereof. Typically the associating agent comprises amixture including the cationic amino-epichlorohydrin adduct such thatthe step of applying the adduct is carried out simultaneously with thestep of applying the associating agent.

The associating agents can be applied to the precursor particles by anyof various techniques and apparatus used for applying solutions tomaterials including coating, dumping, pouring, spraying, atomizing,condensing, or immersing the associating agent on the precursorparticles. The associating agent is applied to at )east a portion of thesurface of at least some of the precursor particles to be bondedtogether. Preferably, the associating agent is coated onto the entiresurface of most, preferably all, of the precursor particles. Theassociating agent is generally mixed with, or sprayed onto, theprecursor particles by any of a number of mixing/spraying techniques andmixing/spraying apparatus to insure that the precursor particles arethoroughly coated with the associating agent.

When an associating agent has been applied to the precursor particles,the precursor particles can be physically contacted together in a numberof different ways. For example, the associating agent alone can hold theparticles together in contact. Alternatively, gravitational forces canbe used to insure contact between the precursor particles, e.g., bylayering precursor particles. Further, the particles can be placed in acontainer having a fixed volume so as to insure contact between theprecursor particles.

The precursor particles can alternatively be physically associatedtogether by physically constraining the precursor particles such thatthey are in contact with each other. For example, the precursorparticles can be packed tightly into a container having a fixed volumesuch that the precursor particles physically contact each other.Alternatively or in combination with the above procedure, gravitationalforces (e.g., layering) can be used to physically associate theprecursor particles. The precursor particles can also be physicallyassociated together by electrostatic attraction or by the introductionof an adhering agent (e.g., an adhesive material such as a water-solubleadhesive) to adhere them together. The precursor particles can also beattached to a third member (a substrate) such that the precursorparticles are brought into contact with each other by the substrate.

In an alternative method of forming the macrostructures of the presentinvention, the aggregate of the precursor particles is shaped intovarious geometries, spatial relationships, and densities to form anaggregate having a defined shape, size, and/or density. The aggregatecan be shaped by any conventional shaping techniques as are known in theart. Preferred methods for shaping the aggregate include casting,molding, or forming operations. Casting and molding techniques generallyinvolve introducing the precursor particles into a prepared mold cavityand applying pressure to (compressing) the aggregate to cause theaggregate to conform to the shape of the mold cavity. Examples ofspecific molding techniques for use herein include compression molding,injection molding, extrusion or laminating. For example, a multiplicityof precursor particles can be added to a container having a fixed volumemold cavity and the aggregate compressed to conform to the shape of themold cavity so that the resultant macrostructure has the same shape.Forming techniques involve performing various operations on theaggregate to modify its shape, and/or size, and/or density. Examples ofspecific forming techniques for use herein include rolling, forging,extruding, spinning, coating or drawing operations. For example, anaggregate mixture of the precursor particles and at least the cationicamino-epichlorohydrin adduct can be passed between a pair of compactionrolls to form an aggregate sheet. Alternatively, the aggregate mixturecan be extruded through an orifice to form an aggregate having a shapecorresponding to that of the the orifice. Further, the aggregate mixturecan be cast on a surface to form an aggregate having a desired shape orsurface morphology. Any or all of these techniques can also be used incombination to form the shaped aggregate. Any suitable apparatus as areknown in the art can be used to carry out such operations, which can beperformed with the material or portions of the apparatus either hotand/or cold.

In an embodiment of the method of the present invention, an aggregatemixture of precursor particles, the cationic amino-epichlorophydrinadduct, water, humectant/co-plasticizer (optional), and a hydrophilicorganic solvent are added to the hopper of a conventional extruderapparatus. An example of an extruder apparatus is shown in FIGS. 12-14of Principles of Polymer Materials, Second Edition, (McGraw Hill BookCompany, 1982) at page 331, which publication is incorporated reference.The aggregate mixture is extruded through the orifice of the extruderapparatus to feed a pair of driven compaction rolls having a fixed (butvariable) gap between the rolls so as to compress the aggregate into theform of a sheet. The sheet is then processed to specific lengths toprovide macrostructures that have a specifically designed size, shapeand/or density.

In forming the aggregate macrostructures of the present invention intoparticular shapes, and especially sheets, the density should becarefully controlled. If the density of the shape aggregatemacrostructure is too high, it can be more prone to gel blocking.Conversely, if the density is too low, the shaped aggregatemacrostructure can have insufficient tensile strength and integrity.Shaped aggregate macrostructures of the present invention usually have adensity of from about 0.7 to about 1.3 g/cc, preferably from about 0.8to about 1.1 g/cc, and most preferably from about 0.9 to about 1.0 g/cc.

A preferred method and apparatus for continuously forming the aggregatemacrostructures of the present invention into sheets is described inU.S. application Ser. No. 935,693, to Michael S. Kolodesh et al,entitled "Method and Apparatus for Making Cohesive Sheets fromParticulate Absorbent Polymeric Composition," filed Aug. 21, 1992, thedisclosure of which is incorporated by reference. This

continuous method for making aggregate sheets can best be understood byreference to FIG. 9 which shows apparatus 301 for carrying it out.Apparatus 301 has frame 302 for supporting its various components.Apparatus 301 comprises a support means, shown in FIG. 9 as movingconveyor 303 which moves in the direction of arrow 310. Conveyor 303first passes under an initial sprayer 304a. After passing under initialsprayer 304a, conveyor 303 passes under at least one means forcontinuously layering a predetermined amount of precursor particles ontothe conveyor. This is shown in FIG. 9 as feeders 305a through 305e.Conveyor 303 also passes under at least one means for spraying apredetermined amount of treatment solution onto the layer of precursorparticles on the conveyor. This is shown in FIG. 9 as sprayers 304bthrough 304f. Apparatus 301 further comprises a pair of non-planaropposing pressure applicators down stream from feeders 305 and sprayers304. The pressure applicators are shown in FIG. 9 as a pair ofcompaction rolls 306. Also shown in FIG. 9 as being part of apparatus301 is a slitting and transfer conveyor 307, knife and anvil rolls 308,and a sheet accumulator 309.

Conveyor 303 can be a flat belt conveyor that has good releaseproperties, such as polyurethane, which is commonly used in the foodindustry. The width of the conveyor is determined by the desired sheetsize. The conveyor generally moves in the direction of arrow 310 frompoint 311, where the initial sprayer 304a is located, to a point 312,where the knife and anvil rolls 308 are located. Conveyor 303 wouldtypically be an endless conveyor as shown in FIG. 9.

Conveyor 303 first passes under an initial sprayer 304a, where theconveyor is sprayed with a predetermined amount of treatment solution soas to cover a predetermined area of the conveyor. This initial sprayinginsures that the bottom part of the first precursor particle layer isexposed to the treatment solution. Also, the wet conveyor surface willprevent the subsequently fed particles from bouncing away from theirdesired placement. However, the initial spraying step is not absolutelynecessary, especially when the first layer of particles to be placed onthe conveyor is relatively thin, or when the conveyor travels at slowerspeeds.

Sprayer 304a (as well as sprayers 304b through 304f) must deliver asubstantially uniform mist, atomized spray and should have a low impactforce to avoid possible blow off of precursor particles. One sprayerthat has been found to work well is a model 6218-1/4 JAU atomized airactuated nozzle assembly, available from Spraying Systems Co., Wheaton,Ill. 60188.

Conveyor 303 then passes under feeder 305a where a predetermined amountof dry precursor particles is layered onto the predetermined area of theconveyor. The amount of precursor particles to be layered onto conveyor303 depends on a number of factors including, but not limited to, thedesired density of the resultant sheet, the number of layering steps tobe performed, the size of the particles being used and the desired widthof the resultant sheet. At a minimum the predetermined amount should beenough to substantially cover a predetermined area of the conveyor witha layer one particle in thickness.

Feeder 305a (as well as feeders 305b through 305e) must be capable ofdistributing the precursor particles in a thin and preferably widelayer. Thinner layers on the conveyor insure that all of the particlesare treated during subsequent spraying steps and wider layers willincrease production output. Vibrating feeders have been shown to beadequate for layering the dry precursor particles onto the conveyor. Anexample of a suitable vibrating feeder is a Super Feeder model#2106E-003S4, commercially available from Solids Flow Control, P.O. Box410767, 14201-A South Lakes Drive, Charlotte, N.C. 28241-0767. Thisfeeder has a weight feed-back control system for accuracy.

Conveyor 303 then passes under a second sprayer 304b. A predeterminedarea of conveyor 303 having the first layer of precursor particles issprayed with a predetermined amount of the same treatment solution usedin initial sprayer 304a. In general, the predetermined amount oftreatment solution is related to the amount of particles in the layer.The greater the amount of particles in the layer, the more treatmentsolution is needed to treat substantially all of the particles.

The metering and spraying steps can then be repeated a number of times(e.g., using feeders 305b through 305e and sprayers 304c through 304f)depending on the desired density of the ultimate sheet. When themetering and spraying steps are repeated a number of times and theinitial spraying step is performed, as described above, the first layerof particles is exposed to two spray applications. Therefore, theinitial spraying step and the first post-layering spraying step eachneed only spray half the amount of treatment solution needed to treatthat amount of particles in the first layer on conveyor 303. The othersprayers 304c through 304f will spray the normal amount of treatmentsolution, i.e. twice the amount of either the initial or firstpost-laying spray.

After all of the layering and spraying steps have been performed, thetreated precursor particles typically loosely adhere together to form aweb. Conveyor 303 then moves this web and delivers it to a pair ofopposing pressure applicators. The pressure applicators shown in FIG. 9take the form of compaction rolls 306. However, as will be appreciatedto those skilled in the art, an intermittent conveyor method could beused, with opposing plates or platens used to compress the web.

Compaction rolls 306 can have a non-planar, rough surface. As the webpasses through compaction rolls 306, the pressure on the web causes itto expand. The rough surface of rolls 306 reduces the sliding effectbetween the rolls and the web in contact with the rolls. This in turnreduces expansion of the web in both the machine direction 310 andcross-machine direction. Machine direction expansion is undesirablebecause it requires compaction rolls 306 to speed up in order to matchthe machine direction expansion. Compaction by rolls 306 densifies theweb of freely deposited layers of precursor particles and sprayedtreatment solution into a sheet.

Compaction rolls 306 can be in the form of cylindrical stainless steelrolls that are coated with a plasma coating, thereby giving the rolls arough surface and causing them to release the web more easily aftercompaction. Examples of suitable coatings include coating #'s 934 and936, available from Plasma Coatings, Inc., Waterbury, Conn. 06702. Thegap between the compaction rolls determines the amount of compactionapplied to the web.

Apparatus 301 can include a slitter to trim the web edges prior tocompaction. The edges of the web can have a less uniform density thanthe rest of the web, and are typically subjected to inconsistentapplication of treatment solution and particles due to the conveyor beltmovement in the cross-machine direction, thus making removal desirable.The slitter can be regular circular knife working against a hard surfacesuch as a transfer conveyor belt, as indicated by 307.

After the web passes through compaction rolls 306, a sheet is formed andcollected in accumulator 309. Accumulator 309 can take the form of awind-up roll that rolls up the sheet into a single roll of a desiredsize. When the desired size roll is obtained apparatus 301 can have asecond slitter to cut the sheet. This second slitter can take the formof knife and anvil roll 308.

Simultaneously or after the cationic amino-epichlorohydrin adduct hasbeen applied, the precursor particles have been physically associatedtogether to form an aggregate, and the aggregate has been shaped, theadduct is reacted With the polymer material of the precursor particles,while maintaining the physical association of the precursor particles,to provide effective surface crosslinking in the precursor particles inthe aggregate macrostructure. Because of the relatively reactivecationic functional groups of the amino-epichlorohydrin adducts used inthe present invention, this crosslinking reaction between the adduct andthe polymer material of the precursor particles can occur at relativelylow temperatures. Indeed, this crosslinking reaction (curing) can occurat ambient room temperatures. Such ambient temperature curing isparticularly desirable when the treatment solution comprising the adductadditionally contains a plasticizer, such as a mixture of water andglycerol. Curing at significantly above ambient temperatures can causethe plasticizer to be driven off due to its volatility, thusnecessitating an additional step to plasticize the resultinginterparticle bonded aggregate. Such ambient curing is typically carriedout at a temperature of from about 18° to about 35° C. for from about 12to about 48 hours. Preferably, such ambient curing is carried out at atemperature of from about 18° to about 25° C. for from about 24 to about48 hours.

Although the crosslinking reaction between the cationicamino-epichlorohydrin adduct and the polymer material of the precursorparticles can occur at ambient temperatures, such curing can also becarried out at higher temperatures to speed up the reaction. Highertemperature curing typically involves heating the treated and associatedprecursor particles to cause the crosslinking reaction between theadduct and the polymer material of the precursor particles to occur in ashorter period of time, typically minutes. This heating step can becarried out using a number of conventional heating devices, includingvarious ovens or dryers well known in the art.

Generally, heat curing can be carried out at a temperature above about50° C. for a period of time sufficient to complete the crosslinkingreaction between the adduct and the polymer material of the precursorparticles. The particular temperatures and times used in heat curingwill depend upon the particular cationic amino-epichlorohydrin adductused and the polymer material present in the precursor particles. If thecure temperature is too low, or the cure time too short, the reactionwill not be sufficiently driven, resulting in macrostructures that haveinsufficient integrity and poor absorbency. If the cure temperature istoo high, the absorbency of the precursor particles can be degraded orthe network crosslinks of these precursor particles, depending upon thespecific polymer materials used, can be degraded to such point that theresulting macrostructure is less useful for absorbing large quantitiesof liquids. In addition, if the cure time and temperatures are notappropriate, extractable levels of the resulting aggregates can begreater, thus increasing the incidence of that particular form ofgel-blocking. Therefore, heat curing is generally carried out at atemperature in the range of front about 50° to about 205° C. for fromabout 1 to about 20 minutes. Preferably, heat curing is carried out at atemperature of from about 180° to about 200° C. for from about 5 toabout 15 minutes. The actual time and temperatures used can varydepending upon the specific polymer materials used in making theprecursor particles, the specific adducts used, the thickness ordiameter of the macrostructure involved, and like factors.

The crosslinking reaction between the cationic amino-epichlorohydrinadduct and the polymer material of the precursor particles issufficiently fast, even at ambient temperatures, such that it can becarried out in the absence of initiators and/or catalysts. However, animportant factor relative to the reactivity of the amino-epichlorohydrinadduct is the pH of the treatment solution containing the adduct.Typically, the pH of the treatment solution is from about 4 to about 9,preferably from about 4 to about 6. Maintenance of the treatmentsolution at a pH within these ranges insures that theamino-epichlorohydrin adduct will be sufficiently reactive, even atambient temperatures.

The physical association of the treated precursor particles needs to bemaintained during the curing step so that, as crosslinking occurs,adjacent precursor particles become cohesively bonded together. Ifforces or stresses are sufficient to disassociate the precursorparticles that are present during the crosslinking reaction,insufficient bonding of the precursor particles can occur. This canresult in aggregates having poor structural integrity. The physicalassociation of the precursor particles is typically maintained byinsuring minimal dissociation forces or stresses are introduced duringthe curing step.

As previously noted, the steps in the method of the present inventionfor producing the macrostructures need not be carried out in anyspecific order, and can be carried out simultaneously. For example, thecationic amino-epichlorohydrin adduct can be applied simultaneously withthe physical association of the precursor particles, shaped into apreferred shape and typically a desired density, and then the adductreacted with the polymer material of the precursor particles, eitherimmediately after the above steps are completed or after the aggregatehas been left standing for a period of time, to simultaneously surfacecrosslink the precursor particles and form the aggregate macrostructure.Typically, the precursor particles are mixed or sprayed with a solutionof the adduct, water, a humectant and/or coplasticizer (e.g., glycerol),and a hydrophilic organic solvent (e.g., methanol) to form an adheredtogether aggregate. The adduct, water, humectant/coplasticizer andhydrophilic organic solvent serve as the associating agent for theprecursor particles, the adduct also serving as the crosslinking agent.The adhered aggregate (i.e. the associated precursor particles and theaqueous mixture) is subsequently shaped into a densified sheet by acombination of extruding and rolling techniques as described above. Theadduct is subsequently reacted with the polymer material by ambient orheat curing to simultaneously cause crosslinking at the surface of theprecursor particles and to form a cohesive interparticle bondedaggregate macrostructure.

Under certain conditions, especially if the treated precursor particleshave been heat cured, the resultant macrostructures can be somewhatinflexible and potentially brittle. In such cases, the macrostructurescan be made more flexible by treating it with a plasticizer. Suitableplasticizers include water, alone or in combination with thehumectants/coplasticizers previously described, preferably glycerol. Theplasticizer can be applied to the macrostructures in a number ofdifferent ways, including spraying, coating, atomizing, immersing, ordumping the plasticizer onto the macrostructure. Alternatively, in thecase of water alone, the macrostructure can be placed in a high humidityenvironment (e.g., greater than 70% relative humidity). The amount ofplasticizer applied to the macrostructure can be selected depending uponthe specific plasticizer used, and the effects desired. Typically, theamount of plasticizer applied is from about 5 to about 100 parts byweight, preferably from about 5 to about 60 parts by weight, per 100parts by weight of the macrostructure. A particularly preferredplasticizer comprises a mixture of glycerol and water in a weight ratioof from about 0.5:1 to about 2:1, preferably from about 0.8:1 to about1.7:1.

As shown in FIGS. 1 through 4 and especially FIGS. 3 and 4, themacrostructures resulting from the method of the present invention havepores (the dark areas of the photomicrograph) between adjacent precursorparticles. The pores are small interstices between adjacent precursorparticles that allow the passage of liquid into the interior of themacrostructure. The pores are formed into the macrostructure because theprecursor particles do not "fit" or pack tightly enough, even whencompressed, to eliminate the pores. (The packing efficiency of theprecursor particles is less than 1.) The pores are generally smallerthan the constituent precursor particles and provide capillaries betweenthe precursor particles to transport liquid into the interior of themacrostructure.

The pores are interconnected with each other by intercommunicatingchannels between the pores. The channels allow liquids contacting themacrostructure to be transported via capillary forces (i.e., capillarychannels are formed) to other portions of the macrostructure so that thetotal volume of the macrostructure is used in absorbing such liquids.Further, when swollen, the pores and the intercommunicating channelsallow liquids to pass through the macrostructure either to layers ofprecursor particles remote from the initial point of liquid contact orto other structures in contact with the macrostructure. Thus, themacrostructure is considered to be liquid permeable due to the pores andthe intercommunicating channels.

The void fraction (i.e., the total volume of the macrostructure thatcomprises the pores and the channels) has a minimum value for a givenprecursor particle size distribution. In general, the narrower theprecursor particle size distribution, the higher the void fraction willbe. Thus, it is preferred, so as to provide higher void fractions in adensified state, that the precursor particles have a relatively narrowparticle size distribution.

Another feature of the macrostructures of the present invention is thatthey swell generally isotropically, even under moderate confiningpressures, when liquids are deposited onto or come into contact withthem. Isotropic swelling is used herein to mean that the macrostructureswells generally equally in all directions when wetted. Isotropicswelling is an important property of the macrostructure because theprecursor particles and the pores are able to maintain their relativegeometry and spatial relationships even when swollen such that theexisting capillary channels are maintained, if not enlarged, during use.(The pores and the precursor particles get larger during swelling.)Thus, the macrostructure can imbibe and/or transport through itselfadditional loadings of liquid while not gel blocking.

An indication that crosslink bonds are being formed at the surface ofthe precursor particles is that the resultant macrostructures are fluid(i.e., liquid) stable. "Fluid stable" is used herein to mean amacrostructure comprising an interparticle bonded aggregate that remainssubstantially intact (i.e., most of the previously independent componentprecursor particles remain bonded together) upon contact with orswelling (with and/or without stress) in an aqueous fluid. While thisdefinition of fluid stability recognizes that most, preferably all, ofthe precursor particles remain bonded together, it, however, should berecognized that some of the precursor particles can dissociatethemselves from the macrostructure if, for example, other particles havebeen subsequently water agglomerated onto it.

Fluid stability is an important feature of the macrostructures of thepresent invention because it allows the aggregate to maintain itsrelative structure in both the dry and swollen states, and because itimmobilizes component precursor particles. In an end product such as anabsorbent member or an absorbent article, fluid stability is beneficialin reducing gel blocking since precursor particles remain aggregatedeven when contacted with liquid, and allows one to use previouslyindependent fine particles in an aggregate form to increase the rate offluid uptake of the resultant macrostructure without introducing theelement of gel blocking.

Fluid stability can be measured in an aggregate macrostructure by a twostep process. The initial dynamic response of the aggregatemacrostructure upon contact with the aqueous fluid is observed and thenthe fully swollen equilibrium condition of the aggregate macrostructureis observed. A test method for determining fluid stability based onthese criteria is hereafter described in the Test Methods section.

In use, liquids that are deposited onto or come in contact with themacrostructures are imbibed by the precursor particles or are passedinto the pores and transmitted to other portions of the macrostructurewhere they are imbibed by other precursor particles or transportedthrough the macrostructure to other absorbent members adjacent thereto.

Various types of fiber material can be used as the reinforcing membersin the macrostructures of the present invention. Any type of fibermaterial which is suitable for use in conventional absorbent products isalso suitable for use in the macrostructures herein. Specific examplesof such fiber material include cellulose fibers, modified cellulosefibers, rayon, polypropylene, and polyester fibers such as polyethyleneterephthalate (DACRON), hydrophilic nylon (HYDROFIL), and the like.Examples of other fiber materials for use in the present invention inaddition to some already discussed are hydrophilized hydrophobic fibers,such as surfactant-treated or silica-treated thermoplastic fibersderived, for example, from polyolefins such as polyethylene orpolypropylene, polyacryl ics, polyamides, polystyrenes, polyurethanesand the like. In fact, hydrophilized hydrophobic fibers which are in andof themselves not very absorbent and which, therefore, do not providewebs of sufficient absorbent capacity to be useful in conventionalabsorbent structures, are suitable for use in the macrostructures of thepresent invention by virtue of their good wicking properties. This isbecause, in the macrostructures herein, the wicking propensity of thefibers is as important, if not more important, than the absorbentcapacity of the fiber material itself due to the high rate of fluiduptake and lack of gel blocking properties of the macrostructures of thepresent invention. Synthetic fibers are generally preferred for useherein as the fiber component of the macrostructure. Most preferred arepolyolefin fibers, preferably polyethylene fibers.

Other cellulosic fiber materials which can be useful in certainmacrostructures herein are chemically stiffened cellulosic fibers.Preferred chemically stiffened cellulosic fibers are the stiffened,twisted, curled cellulosic fibers which can be produced by internallycrosslinking cellulose fibers with a crosslinking agent. Suitablestiffened, twisted, curled cellulose fibers useful as the hydrophilicfiber material herein are described in greater detail in U.S. Pat. No.4,888,093 (Dean et al), issued Dec. 19, 1989; U.S. Pat. No. 4,889,595(Herron et al), issued Dec. 26, 1989; U.S. Pat. No. 4,889,596 (Schoggenet al), issued Dec. 26, 1989; U.S. Pat. No. 4,889,597 (Bourbon et al),issued Dec. 26, 1989; and U.S. Pat. No. 4,898,647 (Moore et al), issuedFeb. 6, 1990, all of which are incorporated by reference.

As used herein, the term "hydrophilic" describes fibers or the surfacesof fibers which are wetted by the liquids deposited onto the fibers(i.e., if water or aqueous body fluid readily spreads on or over thesurface of the fiber without regard to whether or not the fiber actuallyimbibes fluid or forms a gel). The state of the art respecting wettingof materials allows definition of hydrophobicity (and wetting) in termsof contact angles and the surface tension of the liquids and solidsinvolved. This is discussed in detail in the American Chemical SocietyPublication entitled "Contact Angle, Wettability, and Adhesion" editedby Robert F. Gould and copyrighted in 1964. A fiber or surface of afiber is said to be wetted by a liquid either when the contact anglebetween the liquid and the fiber or surface is less than 90° or when theliquid will tend to spread spontaneously across the surface of thefiber; both conditions normally coexisting.

The fiber material can be added to the macrostructures by introducingthe fibers into solution with the cationic amino-epichlorohydrin adduct,by mixing with the precursor particles prior to applying the adduct, orby adding the fiber material to the adduct/precursor particle mixture.For example, the fiber material can be kneaded into the adduct/precursorparticle mixture. The fiber material is preferably thoroughly mixed withthe solution so that the fiber material is uniformly dispersedthroughout the macrostructure. The fibers are also preferably addedbefore reacting the adduct with the polymer material of the precursorparticles.

The relative amount of fiber material mixed with the precursor particlescan vary widely. The fiber material is preferably added in a range fromabout 0.01 parts to about 50 parts, more preferably in the range of fromabout 0.5 parts to about 5 parts, by weight per 100 parts by weight ofthe precursor particles.

E. Uses of Macrostructures

The porous, absorbent macrostructures can be used for many purposes inmany fields of use. For example, the macrostructures can be used forpacking containers; drug delivery devices; wound cleaning devices; burntreatment devices; ion exchange column materials; constructionmaterials; agricultural or horticultural materials such as seed sheetsor water-retentive materials; and industrial uses such as sludge or oildewatering agents, materials for the prevention of dew formation,dessicants, and humidity control materials.

The porous, absorbent macrostructures of the present invention areuseful when joined to a carrier. Carriers useful in the presentinvention include absorbent materials such as cellulose fibers. Thecarriers also can be any other carriers as are known in the art such asnonwoven webs, tissue webs, foams, polyacrylate fibers, aperturedpolymeric webs, synthetic fibers, metallic foils, elastomers, and thelike. The macrostructures can be joined directly or indirectly to thecarriers and can be joined thereto by chemical or physical bonding suchas are known in the art, including adhesives or chemicals that react soas to adhere the macrostructures to the carriers.

Because of the unique absorbent properties of the porous, absorbentmacrostructures of the present invention, they are especially suitablefor use as absorbent cores in absorbent articles, especially disposableabsorbent articles. As used herein, the term "absorbent article" refersto articles which absorb and contain body exudates and more specificallyrefers to articles which are placed against or in proximity to the bodyof the wearer to absorb and contain the various exudates discharged fromthe body. Additionally, "disposable" absorbent articles are those whichare intended to be discarded after a single use (i.e., the originalabsorbent article in its whole is not intended to be laundered orotherwise restored or reused as an absorbent article, although certainmaterials or all of the absorbent article may be recycled, reused, orcomposted). A preferred embodiment of a disposable absorbent article,diaper 20, is shown in FIG. 5. As used herein, the term "diaper" refersto a garment generally worn by infants and incontinent persons that isworn about the lower torso of the wearer. It should be understood,however, that the present invention is also applicable to otherabsorbent articles such as incontinent briefs, incontinent pads,training pants, diaper inserts, sanitary napkins, facial tissues, papertowels, and the like.

FIG. 5 is a perspective view of the diaper 20 of the present inventionin its uncontracted state (i.e., with all the elastic inducedcontraction removed) with portions of the structure being cut-away tomore clearly show the construction of the diaper 20 and with the portionof the diaper 20 which contacts the wearer facing the viewer. The diaper20 is shown in FIG. 5 to preferably comprise a liquid pervious topsheet38; a liquid impervious backsheet 40 joined with the topsheet 38; anabsorbent core 42 positioned between the topsheet 38 and the backsheet40; elastic members 44; and tape tab fasteners 46. While the topsheet38, the backsheet 40, the absorbent core 42, and the elastic members 44can be assembled in a variety of well known configurations, a preferreddiaper configuration is described generally in U.S. Pat. No. 3,860,003(Buell), issued Jan. 14, 1975, which is incorporated by reference.Alternatively preferred configurations for disposable diapers herein arealso disclosed in U.S. Pat. No. 4,808,178 (Aziz et al), issued Feb. 28,1989; U.S. Pat. No. 4,695,278 (Lawson), issued Sep. 22, 1987; and U.S.Pat. No. 816,025 (Foreman), issued Mar. 28, 1989, all of which areincorporated by reference.

FIG. 5 shows a preferred embodiment of the diaper 20 in which thetopsheet 38 and the backsheet 40 are co-extensive and have length andwidth dimensions generally larger than those of the absorbent core 42.The topsheet 38 is joined with and superimposed on the backsheet 40thereby forming the periphery of the diaper 20. The periphery definesthe outer perimeter or the edges of the diaper 20. The peripherycomprises the end edges and the longitudinal edges 30.

The topsheet 38 is compliant, soft feeling, and non-irritating to thewearer's skin. Further, the topsheet 38 is liquid pervious permittingliquids to readily penetrate through its thickness. A suitable topsheet38 can be manufactured from a wide range of materials such as porousfoams, reticulated foams, apertured plastic films, natural fibers (e.g.,wood or cotton fibers), synthetic fibers (e.g., polyester orpolypropylene fibers) or from a combination of natural and syntheticfibers. Preferably, the topsheet 38 is made of a hydrophobic material toisolate the wearer's skin from liquids in the absorbent core 42.

A particularly preferred topsheet 38 comprises staple lengthpolypropylene fibers having a denier of about 1.5, such as Hercules type151 polypropylene marketed by Hercules, Inc. of Wilmington, Del. As usedherein, the term "staple length fibers" refers to those fibers having alength of at least about 15.9 mm (0.62 inches).

There are a number of manufacturing techniques which can be used tomanufacture the topsheet 38. For example, the topsheet 38 can be woven,nonwoven, spunbonded, carded or the like A preferred topsheet is carded,and thermally bonded by means well known to those skilled in the fabricsart. Preferably, the topsheet 38 has a weight from about 18 to about 25grams per square meter, a minimum dry tensile strength of at least about400 grams per centimeter in the machine direction, and a wet tensilestrength of at least about 55 grams per centimeter in the cross-machinedirection.

The backsheet 40 is impervious to liquids and is preferably manufacturedfrom a thin plastic film, although other flexible liquid imperviousmaterials may also be used. The backsheet 40 prevents the exudatesabsorbed and contained in the absorbent core 42 from wetting articleswhich contact the diaper 20 such as bedsheets and undergarments.Preferably, the backsheet 40 is polyethylene film having a thicknessfrom about 0.012 mm (0.5 mil) to about 0.051 centimeters (2.0 mils),although other flexible, liquid impervious materials can be used. Asused herein, the term "flexible" refers to materials which are compliantand which will readily conform to the general shape and contours of thewearer's body.

A suitable polyethylene film is manufactured by Monsanto ChemicalCorporation and marketed in the trade as Film No. 8020. The backsheet 40is preferably embossed and/or matte finished to provide a more clothlikeappearance. Further, the backsheet 40 may permit vapors to escape fromthe absorbent core 42 while still preventing exudates from passingthrough the backsheet 40.

The size of the backsheet 40 is dictated by the size of the absorbentcore 42 and the exact diaper design selected. In a preferred embodiment,the backsheet 40 has a modified hourglass-shape extending beyond theabsorbent core 42 a minimum distance of at least about 1.3 centimetersto about 2.5 centimeters (about 0.5 to about 1.0 inch) around the entirediaper periphery.

The topsheet 38 and the backsheet 40 are joined together in any suitablemanner. As used herein, the term "joined" encompasses configurationswhereby the topsheet 38 is directly joined to the backsheet 40 byaffixing the topsheet 38 directly to the backsheet 40, andconfigurations whereby the topsheet 38 is indirectly joined to thebacksheet 40 by affixing the topsheet 38 to intermediate members whichin turn are affixed to the backsheet 40. In a preferred embodiment, thetopsheet 38 and the backsheet 40 are affixed directly to each other inthe diaper periphery by attachment means (not shown) such as an adhesiveor any other attachment means as known in the art. For example, auniform continuous layer of adhesive, a patterned layer of adhesive, oran array of separate lines or spots of adhesive can be used to affix thetopsheet 38 to the backsheet 40.

Tape tab fasteners 46 are typically applied to the back waistband regionof the diaper 20 to provide a fastening means for holding the diaper onthe wearer. The tape tab fasteners 46 can be any of those well known inthe art, such as the fastening tape disclosed in U.S. Pat. No. 3,848,594(Buell), issued Nov. 19, 1974, which is incorporated by reference. Thesetape tab fasteners 46 or other diaper fastening means are typicallyapplied near the corners of the diaper 20.

The elastic members 44 are disposed adjacent the periphery of the diaper20, preferably along each longitudinal edge 30, so that the elasticmembers 44 tend to draw and hold the diaper 20 against the legs of thewearer. Alternatively, the elastic members 44 can be disposed adjacenteither or both of the end edges 32 of the diaper 20 to provide awaistband as well as or rather than leg cuffs. For example, a suitablewaistband is disclosed in U.S. Pat. No. 4,515,595 (Kievit et al), issuedMay 7, 1985, which is incorporated by reference. In addition, a methodand apparatus suitable for manufacturing a disposable diaper havingelastically contractible elastic members is described in U.S. Pat. No.4,081,301 (Buell), issued Mar. 28, 1978, which is incorporated byreference.

The elastic members 44 are secured to the diaper 20 in an elasticallycontractible condition so that in a normally unrestrained configuration,the elastic members 44 effectively contract or gather the diaper 20. Theelastic members 44 can be secured in an elastically contractiblecondition in at least two ways. For example, the elastic members 44 canbe stretched and secured while the diaper 20 is in an uncontractedcondition. Alternatively, the diaper 20 can be contracted, for example,by pleating, and the elastic members 44 secured and connected to thediaper 20 while the elastic members 44 are in their unrelaxed orunstretched condition.

In the embodiment illustrated in FIG. 5, the elastic members 44 extendalong a portion of the length of the diaper 20. Alternatively, theelastic members 44 can extend the entire length of the diaper 20, or anyother length suitable to provide an elastically contractible line. Thelength of the elastic members 44 is dictated by the diaper design.

The elastic members 44 can be in a multitude of configurations. Forexample, the width of the elastic members 44 can be varied from about0.25 millimeters (0.01 inches) to about 25 millimeters (1.0 inch) ormore; the elastic members 44 can comprise a single strand of elasticmaterial or can comprise several parallel or non-parallel strands ofelastic material; or the elastic members 44 can be rectangular orcurvilinear. Still further, the elastic members 44 can be affixed to thediaper in any of several ways which are known in the art. For example,the elastic members 44 can be ultrasonically bonded, heat and pressuresealed into the diaper 20 using a variety of bonding patterns or theelastic members 44 can simply be glued to the diaper 20.

The absorbent core 42 of the diaper 20 is positioned between thetopsheet 38 and the backsheet 40. The absorbent core 42 can bemanufactured in a wide variety of sizes and shapes (e.g., rectangular,hourglass, asymmetrical, etc.) and from a wide variety of materials. Thetotal absorbent capacity of the absorbent core 42 should, however, becompatible with the design liquid loading for the intended use of theabsorbent article or diaper. Further, the size and absorbent capacity ofthe absorbent core 42 can vary to accommodate wearers ranging frominfants through adults. The absorbent core 42 comprises the porous,absorbent macrostructures of the present invention.

A preferred embodiment of the diaper 20 has a rectangular-shapedabsorbent core 42. As shown in FIG. 6, the absorbent core 42 preferablycomprises an absorbent member 48 comprising an envelope web 50 and aporous, absorbent macrostructure 52 disposed in the envelope web 50. Themacrostructure 52 is encased in the envelope web 50 to minimize thepotential for the precursor particles to migrate through the topsheetand to provide an additional liquid transport layer between the topsheet38 and the macrostructure 52 to enhance liquid acquisition and minimizerewet. As shown in FIG. 6, a single envelope web 50 is wrapped about themacrostructure 52 by folding to form a first layer 54 and a second layer56. The edges 58 of the envelope web 50 are sealed about its peripheryby any conventional means such as an adhesive 59 (as shown), ultrasonicbonds, or heat/pressure bonds, to form a pouch. The envelope web 50 cancomprise a number of materials including nonwoven webs, paper webs, orwebs of absorbent materials such as tissue paper. The envelope web 50preferably comprises a nonwoven web similar to the webs used to form thetopsheet 38. The Donwoven web is preferably hydrophilic to allow liquidsto rapidly pass through the envelope web 50. Similar layered absorbentmembers (laminates) are more fully described in U.S. Pat. No. 4,578,068(Kramer et al), issued Mar. 25, 1986, which is incorporated byreference.

Alternatively, the absorbent cores 42 of the present invention canconsist solely of one or more (a plurality of the) porous, absorbentmacrostructures of the present invention; can comprise a combination oflayers including the macrostructures of the present invention; or anyother absorbent core configurations including one or more of themacrostructures of the present invention.

FIG. 7 shows an alternative embodiment of the diaper 120 comprising adual-layer absorbent core 142 comprising a modified hourglass-shapedabsorbent member 60 and a sheet 62 of the porous, absorbentmacrostructure positioned subjacent the absorbent member 60 (i.e.,between the absorbent member 60 and the backsheet 40).

The absorbent member 60 serves to quickly collect and temporarily holddischarged liquids and to transport such liquids by wicking from thepoint of initial contact to other parts of the absorbent member 60 andto the macrostructure sheet 62. The absorbent member 60 preferablycomprises a web or batt of fiber materials. Various types of fibermaterial can be used i n the absorbent member 60 such as the fibermaterials previously discussed herein. Cellulosic fibers are generallypreferred for use herein, wood pulp fibers being especially preferred.The absorbent member 60 can also contain specific amounts of aparticulate, absorbent, polymeric composition. The absorbent member 60,for example, can contain up to about 50% by its weight of the polymericcomposition. In the most preferred embodiments, the absorbent member 60contains from 0% to about 8% by its weight of a particulate, absorbent,polymeric composition. In alternatively preferred embodiments, theabsorbent member 60 comprises chemically stiffened cellulosic fibers aspreviously discussed herein. Exemplary embodiments of the absorbentmember 60 useful in the present invention are described in U.S. Pat. No.4,673,402 (Weisman et al), issued Jun. 16, 1987; and U.S. Pat. No.4,834,735 (Alemany et al) issued May 30 1989, both of which areincorporated by reference. Absorbent members having a storage zone andan acquisition zone having a lower average density and a lower averagebasis weight per unit area than the storage zone so that the acquisitionzone can effectively and efficiently rapidly acquire discharged liquidare especially preferred for use herein.

The absorbent member 60 can be of any desired shape, for example,rectangular, oval, oblong, asymmetric or hourglass-shaped. The shape ofthe absorbent member 60 can define the general shape of the resultingdiaper 120. In the preferred embodiments as shown in FIG. 7, theabsorbent member 60 is hourglass-shaped.

The macrostructure sheet 62 of the present invention need not be thesame size as the absorbent member 60 and can, in fact, have a topsurface which is substantially smaller or larger than the top surfacearea of the absorbent member 60. As shown in FIG. 7, the macrostructuresheet 62 is smaller than the absorbent member 60 and has a top surfacearea from about 0.10 to about 1.0 times that of the absorbent member 60.Most preferably, the top surface area of the macrostructure sheet 62will be only from about 0.10 to about 0.75, and most preferably fromabout 0.10 to about 0.5 times that of the absorbent member 60. In analternative embodiment, the absorbent member 60 is smaller than themacrostructure sheet 62 and has a top surface area from about 0.25 toabout 1.0 times, more preferably from about 0.3 to about 0.95 times thatof the macrostructure sheet 62. In this alternative embodiment, theabsorbent member 60 preferably comprises chemically stiffened cellulosicfibers, as previously described.

The macrostructure sheet 62 is preferably placed in a specificpositional relationship with respect to the backsheet 40 and/or theabsorbent member 60 in the diaper. More particularly, the macrostructuresheet 62 is positioned generally toward the front of the diaper so thatthe macrostructure sheet 62 is most effectively located to acquire andhold discharged liquids.

In alternatively preferred embodiments, a plurality of macrostructures,preferably from two to six macrostructure strips or sheets, can besubstituted for the single macrostructure sheet 62 shown in FIG. 7.Further, additional absorbent layers, members, or structures can beplaced into the absorbent core 142. For example, an additional absorbentmember can be positioned between the macrostructure sheet 62 and thebacksheet 40 to provide reserve capacity for the absorbent core 142and/or a layer to distribute liquids passing through the macrostructuresheet 62 to other portions of the absorbent core 142 or to themacrostructure sheet 62. The macrostructure sheet 62 can alsoalternatively be positioned over the absorbent member 60 so as to bepositioned between the topsheet 38 and the absorbent member 60.

FIG. 8 shows an alternative embodiment of a diaper 220 comprising analternative dual-layer absorbent core 242 comprising a rectangularshaped absorbent member 260 and three elongated parallel spacedmacrostructure strips 262 positioned between absorbent member 260 andbacksheet 40.

The absorbent member 260 serves to quickly collect and temporarily holddischarged liquids and to transport such liquids by wicking from thepoint of initial contact to other parts of the absorbent member 260 andto macrostructure strips 262. This absorbent member 260 preferablycomprises a web or bat of fiber materials, most preferably chemicallystiffened cellulosic fibers as previously discussed herein.Macrostructure strips 262 together act to acquire and hold thedischarged liquids. By spacing macrostructure strips 262 from oneanother, a more effective surface area is presented for acquiring andholding the discharge liquids. This is particularly true since thespaced macrostructure strips 262 can swell and expand in the directionof their widths without interfering with the ability of adjacent stripsto acquire discharged liquids.

In use, the diaper 20 is applied to a wearer by positioning the backwaistband region under the wearer's back, and drawing the reminder ofthe diaper 20 between the wearer's legs so that the front waistbandregion is positioned across the front of the wearer. The tape-tabfasteners 46 are then secured preferably to outwardly facing areas ofthe diaper 20. In use, disposable diapers or other absorbent articlesincorporating the porous, absorbent macrostructures of the presentinvention tend to more quickly and efficiently distribute and storeliquids and to remain dry due to the high absorbent capacity of themacrostructures. Disposable diapers incorporating the macrostructures ofthe present invention can also be thinner and more flexible.

SYNTHETIC URINE

The specific synthetic urine used in the test methods of the presentinvention is referred to herein as "Synthetic Urine". The SyntheticUrine is commonly known as Jayco SynUrine and is available from JaycoPharmaceuticals Company of Camp Hill, Pa. The formula for the SyntheticUrine is: 2.0 g/l of KCl; 2.0 g/l of Na₂ SO₄ ; 0.85 g/l of (NH₄)H₂ PO₄ ;0.15 g/l (NH₄)₂ HPO₄ ; 0.19 g/l of CaCl₂ and 0.23 g/l of MgCl₂. All ofthe chemicals are of reagent grade. The pH of the Synthetic Urine is inthe range of 6.0 to 6.4.

TEST METHODS A. Absorptive Capacity of the Precursor Particles

The polymeric composition is placed within a "tea bag", immersed in anexcess of Synthetic Urine for a specified period of time, and thencentrifuged for a specific period of time. The ratio of polymericcomposition final weight after centrifuging minus initial weight (netfluid gain) to initial weight determines the Absorptive Capacity.

The following procedure is conducted under standard laboratoryconditions at 23° C. (73° F.) and 50% relative humidity. Using a 6 cm×12cm cutting die, the tea bag material is cut, folded in half lengthwiseand sealed along two sides with a T-bar sealer to produce a 6 cm×6 cmtea bag square. The tea bag material utilized is a grade 1234 heatsealable material, obtainable from C. H. Dexter, Division of the DexterCorp., Windsor Locks, Conn., U.S.A., or equivalent. Lower porosity teabag material should be used if required to retain fine particles. 0.200grams plus or minus 0.005 grams of the polymeric composition is weighedonto a weighing paper and transferred into the tea bag, and the top(open end) of the tea bag is sealed. An empty tea bag is sealed at thetop and is used as a blank. Approximately 300 milliliters of SyntheticUrine are poured into a 1,000 millimeter beaker. The blank tea bag i ssubmerged in the Synthetic Urine. The tea bag containing the polymericcomposition (the sample tea bag) is held horizontally to distribute thematerial evenly throughout the tea bag. The tea bag is laid on thesurface of the Synthetic Urine. The tea bag is allowed to wet, for aperiod of no more than one minute, and then is fully submerged andsoaked for 60 minutes. Approximately 2 minutes after the first sample issubmerged, a second set of tea bags, prepared identically to the firstset of blank and sample tea bags, is submerged and soaked for 60 minutesin the same manner as the first set. After the prescribed soak time iselapsed, for each set of tea bag samples, the tea bags are promptlyremoved (using tongs) from the Synthetic Urine. The samples are thencentrifuged as described below. The centrifuge used is a Delux Dynac IICentrifuge, Fisher Model No. 05-100-26, obtainable from FisherScientific Co. of Pittsburgh, Pa., or equivalent. The centrifuge shouldbe equipped with a direct read tachometer and an electric brake. Thecentrifuge is further equipped with a cylindrical insert basket havingan approximately 2.5 inch (6.35 cm) high outer wall with an 8.435 inch(21.425 cm) outer diameter, a 7.935 inch (20.155 cm) inside diameter,and 9 rows each of approximately 106 3/32 inch (0.238 cm) diametercircular holes equally spaced around the circumference of the outerwall, and having a basket floor with six 1/4 inch (0.635) cm) diametercircular drainage holes equally spaced around the circumference of thebasket floor at a distance of 1/2 inch (1.27 cm) from the interiorsurface of the outer wall to the center of the drainage holes, or anequivalent. The basket is mounted in the centrifuge so as to rotate, aswell as brake, in unison with the centrifuge. The sample tea bags arepositioned in the centrifuge basket with a folded end of the tea bag inthe direction of the centrifuge spin to absorb the initial force. Theblank tea bags are placed to either side of the corresponding sample teabags. The sample tea bag of the second set must be placed opposite thesample tea bag of the first set; and the blank tea bag of the second setopposite the blank tea bag of the first set, to balance the centrifuge.The centrifuge is started and allowed to ramp up quickly to a stablespeed of 1,500 rpm. Once the centrifuge has been stabilized at 1,500rpm, a timer is set for 3 minutes. After 3 minutes, the centrifuge isturned off and the brake is applied. The first sample tea bag and thefirst blank tea bag are removed and weighed separately. The procedure isrepeated for the second sample tea bag and the second blank tea bag. TheAbsorptive Capacity (ac) for each of the samples is calculated asfollows: ac=(sample tea bag weight after centrifuge minus blank tea bagweight after centrifuge minus dry polymeric composition weight) dividedby (dry polymeric composition weight). The Absorptive Capacity value foruse herein is the average Absorptive Capacity of the two samples.

B. Fluid Stability

The objective of this method is to determine the stability of anaggregate upon exposure to Synthetic Urine.

The sample macrostructure is placed in a shallow dish. An excess amountof Synthetic Urine is added to the macrostructure. The swelling of themacrostructure is observed until equilibrium is reached. During theobservation of the swelling macrostructure, the macrostructure isobserved for small particles breaking off from the main aggregate,platelet-like particles floating away from the main aggregate, orparticle expansion only in the two dimensional x-y plane with particlesbreaking and floating away from the main aggregate. If the aggregate hasa large number of broken away component particles, the macrostructure isconsidered unstable. The macrostructure should also be observed forisotropic swelling. If the aggregate remains relatively stable and therelative geometry and spatial relationships of the precursor particlesand the pores are maintained after the test procedure, themacrostructure is considered stable. Preferably, fluid stablemacrostructures are capable of being picked up in their swollen statewithout breaking apart.

C. Precursor Particle Size and Mass Average Particle Size

The particle size distribution on a weight percent basis of a 10 grambulk sample of the precursor particles is determined by sieving thesample through a set of 19 sieves ranging in size from a standard #20sieve (850 microns) through a standard #400 sieve (38 microns). Thesieves are standard sieves as obtainable from the Gilson Company, Inc.of Worthington, Ohio. The procedure is carried out on three stacks ofsieves at a time since the equipment used cannot hold all 19 sieves atone time. A first stack contains sieves #20, 25, 30, 35, 40, 45, and 50plus the sieve pan; the second stack contains sieves #60, 70, 80, 100,120, and 140 plus the sieve pan; the third stack contains sieves #170,200, 230, 270, 325, and 400 plus the sieve pan. The precursor particlesremaining on each of these sieves are then weighed to determine theparticle size distribution on a weight percent basis.

The first stack of sieves is mounted on a shaker and 10.0 grams plus orminus 0.00 grams of the sample is placed on the #20 sieve. The shakerused is a Vibratory 3-inch Sieve Shaker Model SS-5 as obtainable fromthe Gilson Company, Inc. of Worthington, Ohio. The stack is shaken for 3minutes at approximately 2100 vibrations per minute ("6" on theinstrument dial). The sieve pan is then removed and the stack set asidefor later weighing. Using a soft brush, the sample remaining on thesieve pan is transferred onto a weighing paper. The second stack ofsieves is mounted on the shaker and the sample on the weighing paper istransferred onto the #60 sieve. The second stack is shaken for 3 minutesat approximately 2100 vibrations per minute, the sample remaining on thesieve pan being transferred to a weighing paper and the stack set aside.The third stack of sieves is mounted on the shaker and the sample on theweighing paper is transferred onto the #170 sieve. The third stack isshaken for 3 minutes at approximately 2100 vibrations per minute. A softbrush is used to transfer the contents of each given sieve onto a taredweighing paper. The sample is weighed on a standard three place scaleand the weight of the sample on the specific sieve is recorded. Thisstep is repeated, using a fresh weighing paper for each sample, for eachsieve, and for the sample remaining on the sieve pan after the thirdstack of sieves has been shaken. The method is repeated for twoadditional 10 gram samples. The average of the weights of the threesamples for each sieve determine the average particle size distributionon a weight percent basis for each sieve size.

The Mass Average Particle Size of the 10 gram bulk sample is calculatedas follows: ##EQU1## wherein maps is the mass average particle size; Miis the weight of the particles on the specific sieve; and D_(i) is the"size parameter" for the specific sieve. The size parameter, D_(i) of asieve is defined to mean the size (in microns) of the next highestsieve. For example, a standard #50 sieve has a size parameter of 355microns, which corresponds to the size of the openings in a standard #45sieve (the next highest sieve). The Mass Average Particle Size for useherein is the average of the mass average particle size of the threesamples.

Precursor Particle Example

A jacketed 10 liter twin arm stainless steel kneader measuring 220mm×240 mm in the opening and 240 mm in depth, and having two Sigma typeblades possessing a rotational diameter of 120 mm is sealed with a lid.An aqueous monomer solution is prepared consisting of 37 weight %monomer. The monomer consists of 75 mole % sodium acrylate and 25 mole %acrylic acid. 5500 grams of the aqueous monomer solution is charged tothe kneader vessel, which is subsequently purged with nitrogen gas toremove the remaining entrapped air. Then, the two Sigma type blades areset rotating at rates of 46 rpm and the jacket is heated by the passageof 35° C. water. 2.8 g of sodium persulfate and 0.14 g of L-ascorbicacid are added as polymerization initiators. Polymerization begins aboutfour minutes after the addition of the initiators. A peak temperature of82° C. is reached inside the reaction system 15 minutes after theaddition of the initiators. The hydrated gel polymer is divided intoparticles about 5 mm in size as the stirring is continued. The lid isremoved from the kneader 60 minutes after the start of thepolymerization and the material is removed from the kneader.

The resultant hydrated aqueous gel polymer thus obtained is spread on astandard #50 size metal gauze and dried with hot air at 150° C. for 90minutes. The dried particles are pulverized with a hammer type crusherand sifted with a standard #20 sieve 850 microns) to obtain particlesthat pass through the standard #20 sieve. The mass average particle sizeof these particles is 405 microns.

Specific Illustrations of Preparation of Macrostructures According toPresent Invention EXAMPLE 1

One hundred parts of precursor particles made in accordance with thePrecursor Particle Example are placed into a 5 quart standingkitchen-type mixer. The precursor particles have a particle size suchthat the precursor particles pass through a standard No. 50 sieve (300microns) and are retained on a standard No. 100 sieve (150 microns). Anaqueous treatment solution is prepared from a mixture of 4.3 partsKymene Plus (30% resin active), 2.6 parts water and 10.0 parts methanol.This treatment solution is sprayed onto the precursor particles with aPreval sprayer (available from The Precision Valve Corporation ofYonkers, N.Y.). The treatment solution is sprayed onto the precursorparticles, while the mixer is operating at slow speed, for a period ofabout 4 minutes, i.e. until all of the solution is sprayed onto theparticles. After spraying, the mixture of wet precursor particles ismixed at the highest speed setting for 2 to 5 minutes. During this highspeed mixing, the methanol is evaporated, thus increasing the stickinessof the treated mixture of precursor particles so that they will remainadhered together. This sticky mixture of treated precursor particles isthen fed to an extrusion/compaction unit. The extruder screw has alength of 8 inches (20.3 cm) and contains 5 flights, each flight being1.5 inches (3.8 cm) in length. The outside diameter of the extruderscrew is 1.75 inches (4.45 cm) and the screw-to-housing clearance is0.20 inches (0.51 cm). The unit is activated such that the extruderscrew turns at a rate of 47 rpm. The mixture is extruded between twosmooth finish steel compaction rolls (nip rolls) with a fixed (butvariable) gap. The compaction rolls have a diameter of 8.975 inches(22.8 cm) and are driven at a rate of 5.4 rpm. The gap between thecompaction rolls is 0.015 inches (0.38 mm). The formed aggregate sheetsare then separated into approximately 12 to 15 inch (30 to 40 cm)lengths. The resultant aggregate sheets are heated in a forced airconvection oven at 200° C. for about 10 minutes so that the Kymene Plusreacts with the polymer material in the surface of the precursorparticles, thus causing effective crosslinking. The oven-cured sheetshave a thickness (caliper) of about 0.031 inches (0.8 mm) and a width ofabout 1.95 inches (4.95 cm). A plasticizer solution containing 65 partsglycerol and 35 parts distilled water is sprayed onto the oven-curedsheets at the rate of 0.9 g. of plasticizer solution, per 1.0 g. of theoven-cured sheet. About 1/2 hour after treatment with the plasticizersolution, the sheets have sufficient flexibility and tensile strength tobe picked up.

EXAMPLE 2

In this example, 100 parts of precursor particles made in accordancewith the precursor particle example and having the particle sizecharacteristics described in Example 1 are used. An aqueous treatmentsolution prepared from a mixture of 6.0 parts Kymene Plus (30% resinactive), 3.5 parts water and 8.5 parts glycerol is also used.

A reciprocating table or shuttle is used in conjunction with a pair ofsprayers that apply the treatment solution and a vibratory feeder thatdeposits the precursor particles. The sprayers and feeder are positionedabove the reciprocating surface of the table. As the surface of thistable moves underneath the sprayers, the treatment solution is sprayedonto the table surface (or layer of particles) in a predeterminedpattern. As the surface of the table moves further in the same directionand underneath the feeder, a predetermined amount of precursor particlesare deposited onto the table surface or previous layer of treatedparticles. After the particles have been deposited from the feeder toform a layer thereof, the surface of the table moves back in theopposite direction so that the sequence of applying treatmentsolution/depositing a layer of particles can be repeated.

Initially, a predetermined amount of the treatment solution is sprayedonto the moving surface of the table. After the surface of the table hasbeen initially sprayed with treatment solution, five layers of precursorparticles (0.2 g./in² of particles per layer) are deposited from thefeeder. After each layer of precursor particles has been deposited, apredetermined amount of the treatment solution is sprayed on top of eachlayer. The amount of treatment solution sprayed initially onto thesurface of the table, as well as the first layer of precursor particles,is about 0.018 g/in². The amount of treatment solution sprayed onto theother four layers of precursor particles is about 0.036 g/in². Ineffect, each layer of precursor particles is treated with the sameamount of solution.

After the layering of precursor particles and spraying with treatmentsolution is complete, a relatively cohesive sheet of particles isformed. This cohesive sheet is then fed by a belt to a compaction unit.The compaction unit consists of two coated steel compaction rolls (niprolls) with a fixed (but variable) gap. The compaction rolls have adiameter of about 8 inches (20 cm) and are driven at a rate of about 20rpm. The gap between the compaction rolls is 0.035-0.040 inches (0.9-1.0mm). The resultant aggregate sheets (density of 0.9-1.0 g/cc) are storedin plastic bags at ambient room temperature (about 65°-72° F.,18.3°-22.2° C.) for about 24 hours. During this ambient temperaturecuring, the Kymene Plus reacts with the polymer material in the surfaceof the precursor particles, thus causing effective crosslinking. Theambient temperature cured sheets have a thickness (caliper) of about0.050-0.060 inches (1.3-1.5 mm) and a width of about 4 inches (10 cm).These ambient temperature cured sheets have sufficient flexibility andtensile strength to be handled without breaking or tearing.

EXAMPLE 3

In this example, apparatus 301 shown in FIG. 9 is used. The precursorparticles used are made in accordance with the precursor particleexample and have a size between 150-250 microns. An aqueous treatmentsolution is prepared from a mixture of 5.0 parts Kymene Plus (30% resinactive), 7.1 parts of water and 12.7 parts glycerol. Feeders 305 areSuper Feeder model #210 SE-00354 vibrating feeders, available fromSolids Flow Control, of Charlotte, N.C. Sprayers 304 are model 6218-1/4JAU atomized air actuated nozzle assemblies, available from SprayingSystems, Co., of Wheaton, Ill. For the first two applications, sprayers304a and 304b deliver the treatment solution to conveyor 303 at a rateof 39.8 grams/min. For subsequent applications, sprayers 304c through304f deliver the treatment solution to conveyor 303 at a rate of 79.6grams/min. Conveyor 303 is a moving conveyor made from polyurethane, andtravels at a speed of 27 ft./min. The pressure applicators are a pair ofcompaction rolls 306 having 8 inch (20 cm) diameters and being 12 inches(30.5 cm) wide. The top and bottom rolls 306 are coated with a #934Plasma Coating, available from Plasma Coatings, Inc., of Waterbury,Conn.

This example is carried out according to the following steps:

STEP 1: Initially spray a predetermined area of the conveyor withtreatment solution in an amount substantially equal to 0.025 grams ofsolution per square inch of the conveyor.

STEP 2: Layer substantially continuously 0.2 grams of precursorparticles per square inch of the conveyor onto the same predeterminedarea.

STEP 3: The first layer of precursor particles on the predetermined areaof the conveyor is sprayed with treatment solution in an amountsubstantially equal to 0.025 grams of solution per square inch ofconveyor.

STEP 4: Layer substantially continuously 0.2 grams of precursorparticles per square inch of the conveyor onto the same predeterminedarea.

STEP 5: The second layer of precursor particles on the predeterminedarea of the conveyor is sprayed with treatment solution in an amountsubstantially equal to 0.050 grams of solution per square inch of theconveyor.

STEP 6: Steps 4 and 5 are repeated, in order, 3 more times, giving: (a)a total of one initial spraying step and five post-layering sprayingsteps for a total of 0.25 grams of treatment solution per square inch ofthe conveyor; and (b) a total of five layering steps for a total of 1gram of precursor particles per square inch of the conveyor. A web isnow formed.

STEP 7: The web is passed through the compaction rolls. The gap betweenthe compaction rolls is 0.035 inches (0.9 mm). This produces a sheethaving a density of 0.995 g/cc.

STEP 8: The sheet is cured by placing it in a plastic bag and allowingit to sit at ambient temperature (72° F., 22.2° C.) for 48 hours.

The resultant sheet has good flexibility, gel blocking and wet integrityproperties.

What is claimed is:
 1. A porous, absorbent macrostructure comprising aninterparticle bonded aggregate comprising:(i) a multiplicity ofprecursor particles bonded to each other at the surface thereof andcomprising a substantially water-insoluble, absorbent, hydrogel-forming,polymer material having anionic functional groups, and (ii) a cationicamino-epichlorohydrin adduct reacted with said polymer material at saidsurface of said precursor particles and in an amount sufficient to causeeffective surface crosslinking;said interparticle bonded aggregatehaving pores between adjacent precursor particles, said pores beinginterconnected by intercommunicating channels so as to form a liquidpermeable macrostructure, the circumscribed dry volume of themacrostructure being greater than about 0.008 mm³.
 2. The macrostructureof claim 1 which has a circumscribed volume greater than about 10 mm³.3. The macrostructure of claim 2 which has a circumscribed volumegreater than about 500 mm³ and a density of from about 0.7 to about 1.3g/cc.
 4. The macrostructure of claim 3 wherein said precursor particleshave a mass average particle size less than about 600 microns.
 5. Themacrostructure of claim 4 wherein said precursor particles have a massaverage particle size less than about 300 microns.
 6. The macrostructureof claim 5 which is a sheet having a thickness of at least about 0.2 mmand a density of from about 0.8 to about 1.1 g/cc.
 7. The macrostructureof claim 6 which further comprises from about 5 to about 100 parts byweight of a plasticizer, per 100 parts by weight of said precursorparticles.
 8. The macrostructure of claim 7 wherein said plasticizercomprises a mixture of glycerol and water in a weight ratio of fromabout 0.5 to about 2:1.
 9. The macrostructure of claim 2 wherein saidanionic functional groups of said polymer material are carboxy groups.10. The macrostructure of claim 9 wherein said polymer material isselected from the group consisting of hydrolyzed starch-acrylonitrilegraft copolymers; partially neutralized starch-acrylonitrile graftcopolymers; starch-acrylic acid graft copolymers, partially neutralizedstarch-acrylic acid graft copolymers; saponified vinyl acetate-acrylicester copolymers; hydrolyzed acrylonitrile copolymers;. hydrolyzedacrylamide copolymers; slightly network crosslinked products of any ofthe foregoing copolymers; partially neutralized polyacrylic acid;slightly network crosslinked products of partially neutralizedpolyacrylic acid; and mixtures thereof.
 11. The macrostructure of claim9 wherein said cationic amino-epichlorohydrin adduct is a cationicpolymeric amino-epichlorohydrin resin in an amount from about 0.1 toabout 5 parts by weight, per 100 parts by weight of said precursorparticles.
 12. The macrostructure of claim 11 wherein said cationicpolymeric resin is a reaction product between epichlorohydrin and apolyethyleneimine or a polyamide-polyamine.
 13. The macrostructure ofclaim 12 wherein said cationic polymeric resin is a reaction productbetween epichlorohydrin and a polyamide-polyamine derived frompolyalkylene polyamines and C₃ -C₁₀ dibasic carboxylic acids.
 14. Themacrostructure of claim 13 wherein said polyamide-polyamine is derivedfrom polyethylene polyamine having from 2 to 4 ethylene units and a C₄-C₆ saturated aliphatic dicarboxylic acid, and wherein said cationicpolymeric resin is in an amount of from about 0.5 to 2.5 parts byweight, per 100 parts by weight of said precursor particles.
 15. Themacrostructure of claim 14 wherein said polyamide-polyamine is derivedfrom diethylenetriamine and adipic acid.
 16. An absorbent articlecomprising a liquid pervious topsheet; a liquid impervious backsheetjoined with said topsheet; and an absorbent core positioned between saidtopsheet and said backsheet, said absorbent core comprising one or moreof the macrostructures of claim
 1. 17. The absorbent article of claim 16wherein said absorbent core additionally comprises an absorbent memberpositioned between said topsheet and said macrostructure, said absorbentmember comprising chemically stiffened cellulosic fibers.
 18. Theabsorbent article of claim 17 which is a diaper.
 19. A flexible, porous,absorbent sheet having a thickness of at least about 0.2 mm and adensity of from about 0.8 to about 1.1 g/cc, and comprising aninterparticle bonded aggregate comprising:(i) a multiplicity ofprecursor particles having a mass average particle size less than about300 microns bonded to each other at the surface thereof and comprising asubstantially water-insoluble, absorbent, hydrogel-forming, polymermaterial having carboxy groups; (ii) a cationic polymorphicamino-epichlorohydrin resin in an amount of from about 0.1 to about 5parts by weight, per 100 parts by weight of said precursor particles,said cationic polymeric resin being reacted with said polymer materialat said surface of said precursor particles so as to form estercrosslink bonds; (iii) a plasticizer in an amount of from about 5 toabout 60 parts by weight, per 100 parts by weight of said precursorparticles;said interparticle bonded aggregate having pores betweenadjacent precursor particles, said pores being interconnected byintercommunicating channels so as to form a liquid permeable sheet, thecircumscribed dry volume of the sheet being greater than about 500 mm³.20. The sheet of claim 19 which has a thickness between about 0.5 mm andabout 10 mm.
 21. The sheet of claim 20 which has a thickness betweenabout 1 mm and about 3 mm and a density of from about 0.9 to about 1.0g/cc.
 22. The sheet of claim 20 wherein said polymer material isselected from the group consisting of hydrolyzed starch-acrylonitrilegraft copolymers; partially neutralized starch-acrylonitrile graftcopolymers; starch-acrylic acid graft copolymers, partially neutralizedstarch-acrylic acid graft copolymers; saponified vinyl acetate-acrylicester copolymers; hydrolyzed acrylonitrile copolymers; hydrolyzedacrylamide copolymers; slightly network crosslinked products of any ofthe foregoing copolymers; partially neutralized polyacrylic acid;slightly network crosslinked products of partially neutralizedpolyacrylic acid; and mixtures thereof.
 23. The sheet of claim 22wherein at least about 95% by weight of said precursor particles have aparticle size between about 150 microns and about 300 microns.
 24. Thesheet of claim 22 wherein said cationic polymeric resin is a reactionproduct between epichlorohydrin and a polyethyleneimine or apolyamide-polyamine.
 25. The sheet of claim 24 wherein said cationicpolymeric resin is a reaction product between epichlorohydrin and apolyamide-polyamine derived from polyalkylene polyamines and C₃ -C₁₀dibasic carboxylic acids.
 26. The sheet of claim 25 wherein saidpolyamide-polyamine is derived from a polyethylene polyamine having from2 to 4 ethylene units and a C₄ -C₆ saturated aliphatic dicarboxylic acidand wherein said cationic polymeric resin is in an amount of from about0.5 to about 2.5 parts by weight, per 100 parts by weight of saidprecursor particles.
 27. The sheet of claim 26 wherein saidpolyamide-polyamine is derived from diethylenetriamine and adipic acid.28. The sheet of claim 26 wherein said plasticizer comprises a mixtureof glycerol and water in a weight ratio of from about 0.5:1 to about2:1.
 29. The sheet of claim 28 wherein said plasticizer is in an amountfrom about 10 to about 30 parts by weight, per 100 parts by weight ofsaid precursor particles.
 30. An absorbent article comprising a liquidpervious topsheet; a liquid impervious backsheet joined with saidtopsheet; and an absorbent core positioned between said topsheet andsaid backsheet, said absorbent core comprising one or more absorbentstructures formed from the sheet of claim
 19. 31. The absorbent articleof claim 30 wherein said absorbent core additionally comprises anabsorbent member positioned between said topsheet and said absorbentstructures, said absorbent member comprising chemically stiffenedcellulosic fibers.
 32. The absorbent article of claim 31 wherein saidabsorbent structures comprise from two to six elongated parallel spacedstrips.
 33. The absorbent article of claim 32 which is a diaper.